Reaction of a mixture of 1,1-bis(cyclopentadienyl)cyclohexane and pentamethylenefulvene with metallic sodium in THF led to a mixture of cyclohexylidene-bridged bis(cyclopentadienyl)sodium and two-cyclohexylidenebridge...
the National Natural Science Foundation of China (51173018);the National Basic Research Program of China (973 program, 2013CB834704)
Luminescent materials exhibiting emission switching in the solid state have drawn much attention though there is still no clear design strategy for such materials. In this letter, we reported the crystallization induc...
supported by the National Natural Science Foundation of China.
<正> Exo-cyclic double-bond addition of 6,6-dialkylfulvene and 6,6-polymethylenefulvene withα-pyridylmethyllithium (α-picolinyllithium) results in substituted cyclopentadienyl lithium,which is hy-drolyzed or reacted...
Supported by the National Natural Science Foundation of Shandong Province
The substituted cyclopentadienyl-magnesium-chloride, obtained by exocyclic addition of 6,6-dialkylfulvene and allyl-magnesium-chloride, reacted with the ketone 3, the product was hydrolyzed and dehydrated to give the ...
Project supported by the National Natural Science Foundation of China.
The steric hindrance effect of the reaction of 6,6-dialkylfulvenes and 6,6-polymethylene-fulvenes withethyllithium,n-butyllithium,i-butyllithium,cyclopentyllithium,cyclohexyllithium and metal lithium is brief-ly explo...
Additive reactions of α-thienyllithium with 6,6-dimethylfulvene,6-methyl-6-ethylfulvene and 6,6-pentametbylenefulvene result in exo-double bond addition,β-Thienyllithium only undergoes additive re- 'action with 6,6-...