Pd(OAc)_(2)/PPh_(3)-Catalyzed Desulfonylative Homocoupling of Arylsulfonyl Chlorides  

作　　者：Qiao Zhao Liangshun Chen Hongyue Lang Shengying Wu Limin Wang 

机构地区：[1]Shanghai Key Laboratory of Functional Materials Chemistry,East China University of Science and Technology,Shanghai 200237,China [2]Key Laboratory of Organofluorine Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032,China

出　　处：《Chinese Journal of Chemistry》2015年第5期535-538,共4页中国化学（英文版）

基　　金：the National Natural Science Foundation of China(Nos.21272069,20672035);the Fundamental Research Funds for the Central Universities,and the Key Laboratory of Organofluorine Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences.

摘　　要：The Pd-catalyzed homodimerization with respect to arylsulfonyl chlorides as an efficient method for the synthesisof biaryls has been developed. This desulfonylative reaction which was performed at reflux in 1,4-dioxane for 4h under air afforded the desired products in good to excellent yields.

关 键 词：BIARYLS arylsulfonyl chlorides desulfonylative PALLADIUM-CATALYZED 

分 类 号：O64[理学—物理化学]