Chiral porphyrin assemblies  

作　　者：Li Zhang TianyuWang Jianzhuang Jiang Minghua Liu 

机构地区：[1]Beijing National Laboratory for Molecular Science(BNLMS),CAS Key Laboratory of Colloid,Interface and Chemical Thermodynamics,Institute of Chemistry,Chinese Academy of Sciences,Beijing,P.R.China [2]Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials,Department of Chemistry,University of Science and Technology Beijing,Beijing,P.R.China

出　　处：《Aggregate》2023年第1期27-40,共14页聚集体（英文）

基　　金：National Natural Science Foundation of China,Grant/Award Numbers:92156018,21972150,21890734;CAS Project for Young Scientists in Basic Research,Grant/Award Number:YSBR-027。

摘　　要：Porphyrins are among the most important macrocycles because they perform many essential functions in living systems and serve as building blocks in many functional materials.Incorporating the chirality into porphyrins can aid biomimetic research and the exploration of new functional materials.In this review,recent developments in chiral porphyrin assemblies are highlighted.The review is mainly divided into two sections:the different strategies for constructing chiral porphyrin assemblies and the applications.The formation of chiral porphyrin assemblies can be from porphyrin molecules substituted with chiral groups;achiral porphyrins induced by chiral additives and spontaneous deracemizations of achiral porphyrins during the assemblies.We also provide an overview of the applications of chiral porphyrin assemblies in chiral sensing,asymmetry catalysis,circularly polarized luminescence,and so on.The further challenge in the field is discussed.

关 键 词：CHIRAL circularly polarized luminescence HELICAL PORPHYRINS SELF-ASSEMBLY 

分 类 号：O62[理学—有机化学]