supported by the National Natural Science Foundation of China(Nos.22278451 and 21938001);Guangdong Basic and Applied Basic Research Foundation(2022B1515120057,2019A1515110979)
The development of green route for preparing propylene oxide(PO)with molecular oxygen is of significance both in academic and industrial.In this work,propylene epoxidation coupled with furfural oxidation catalyzed by ...
supported by the RA MESCS Science Committee and Belarusian Republican Foundation for Fundamental Research in the frames of the joint research project SC No.21SC-BRFFR-1F007 and BRFFR Grant No.21ARM-014 accordingly,as well as from the Ministry of Science and Higher Education of Russian Federation within the framework of a state assignment(project No.FSRR-2023-0007)。
Using a photosensitizer(PS),light,and oxygen,photodynamic therapy creates cytotoxic reactive oxygen species,such as singlet oxygen(1O2),that kill cancer cells.Many cancer cell lines have up to 300 times more folic aci...
The use of three-dimensional self-assembled metallacages(MCgs)as multimodal drug platforms holds great promise.However,the synthesis of MCgs with increased complexity and functionality is a great challenge since under...
CONACYT for financial support of this research through the projects:Catedras CONAHCYT 1060 and Paradigmas y Fronteras de la Ciencia 320379.
In this review,the possibilities of photochemical and electrochemical water splitting(WS)using porphyrins,phthalocyanines,related macrocycles,and their metal complexes are discussed.Significant efforts are being carri...
financial support from the Russian Science Foundation (project N 21-13-00221)for the synthesis and studies of optical and magnetic properties of 1;supported by the Ministry of Science and Higher Education of the Russian Federation (Registration number 124013100858-3);E.N.I.and M.K.I.acknowledge Grant from the Ministry of Science and Higher Education of the Russian Federation (no.075-15-2021-579)for synthesis of H3Hhp and preliminary DFT calculations;support from the Spanish MCIN/AEI/10.13039/501100011033 (PID2020-116490GB-I00,TED2021-131255B-C43);the Comunidad de Madrid,and the Spanish State through the Recovery,Transformation and Resilience Plan[“Materiales Disruptivos Bidimensionales (2D)” (MAD2D-CM) (UAM1)-MRR Materiales Avanzados],and the European Union through the Next Generation EU funds.Instituto madrileno de estudios avanzados Nanociencia acknowledges support from the“Severo Ochoa”Programme for Centres of Excellence in R&D (Ministerio de asuntos economicos y transformacion digital,Grant SEV2016-0686).
The complexation of high-spin lanthanides to porphyrinoids is a powerful strategy for the development of advanced molecular magnets.In this context,the use of expanded porphyrinoids remains elusive since their coordin...
In the past decades,porphyrins,phthalocyanines and related materials have attracted significant attention due to their diverse and brilliant structures[1,2],as well as their unique electronic structures and photophysi...
the Deutsche Forschungsgemeinschaft(STA 511/15e1 and-2)is gratefully acknowledged.
Determining the dynamics of adsorbed liquids on nanoporous materials is crucial for a detailed understanding of interactions and processes on the solid-liquid interface in many materials and porous systems.Knowledge o...
We acknowledge the National Natural Science Foundation of China(No.22075116);Fundamental Research Funds for the Central Universities of China(No.lzujbky-2021-ey10);Science and Technology program of Gansu Province(No.20JR5RA305).
Phase transition and phase separation of formamidinium-cesium(FA-Cs)perovskite during the fabrication and operation processes reduce the efficiency and stability of perovskite solar cells(PSCs).Here,we develop an in s...
Science,Technology and Innovation Committee of Shenzhen Municipality,Grant/Award Number:JCYJ20180507183413211;RGC Senior Research Fellowship Scheme,Grant/Award Number:SRFS2021-5S01;National Natural Science Foundation of China,Grant/Award Number:52073242;Hong Kong Polytechnic University;General Research Fund,Grant/Award Number:12304320;Hong Kong Research Grants Council。
One of the major obstacles of porphyrins is the aggregation-caused quenching(ACQ)of photoluminescence due to the strong intermolecularπ–πinteraction of the planar porphyrin core in the solid state.However,ACQ leads...
The authors thank the Research Center of Analysis and Test of East China University of Science and Technology for compound characterization.
Suitable conformations and proper alignment of complex natural macrocycles are essential for achieving their unique properties.However,such artificial macrocycle prototypes are still limited due to synthetic difficult...