supported by the National Natural Science Foundation of China(Nos.22271140,22071103,and 22371118)。
Preparing free-base porphyrinoid radicals that can function as coordination ligands is a challenging task.Here we report the synthesis of a stable,free-base benzocorrole(BC)radical containing only two inner NH protons...
T.T.acknowledges financial support from the Spanish MCIN/AEI/10.13039/501100011033(PID2020-116490GBI00,TED2021-131255B-C43);the Comunidad de Madrid and the Spanish State through the Recovery,Transformation and Resilience Plan[“Materiales Disruptivos Bidimensionales(2D)”(MAD2D-CM)(UAM1)-MRR Materiales Avanzados];the European Union through the Next Generation EU funds.Instituto madrileno de estudios avanzados Nanociencia acknowledges support from the“Severo Ochoa”Programme for Centres of Excellence in R&D(Ministerio de asuntos economicos y transformacion digital,Grant SEV2016-0686);T.T.also acknowledges the Alexander von Humboldt Foundation(Germany)for the A.v.Humboldt-J.C.Mutis Research Award 2023(Ref 3.3-1231125-ESP-GSA);J.L.acknowledgesMinisterio de Eduacion,Cultura y Deporte(MECD),Spain,for an F.P.U.Fellowship.
Over the past few years,the development of nonfullerene acceptors(NFAs)has become a prominent focus in both organic and perovskite solar cell(OSCs and PSCs,respectively)research fields.In this context,porphyrinoids,co...
supported by the National Natural Science Foundation of China(Nos.22071103,22001119 and 21911540069);the Program A for Outstanding PhD Candidate of Nanjing University(No.202201A006).
Materials with facilely tunable spin configurations based on metal-radical coordination systems have potential applications for electronics and spintronics.Here,we report the ground state conversion of copper corrole ...
The authors thank the Research Center of Analysis and Test of East China University of Science and Technology for compound characterization.
Suitable conformations and proper alignment of complex natural macrocycles are essential for achieving their unique properties.However,such artificial macrocycle prototypes are still limited due to synthetic difficult...
supported by the National Natural Science Foundation of China(22071103,21911540069 to Z.S.and22001119 to F.W.)。
Designing stable molecules with efficient near-infrared(NIR) photothermal/photoacoustic performances is important for biological and environmental applications.In this article,we inserted paramagnetic Cu(Ⅱ) into tetr...
the National Nature Science Foundation of China(Nos.21672006,21672007 and 21871006)for supporting this work
Novel expanded porphyrinoids with advanced structure features(such as multiple-inner-ring-fusion)have a wide range of benefits(such as multi-metal coordination and facile tunable aromaticity)not offered by their norma...
Support from the National Natural Science Foundation of China (Nos. 21501070, 21071067), Jiangsu University Foundation (Nos. 05JDG051, 15JDG131) and the Robert A. Welch Foundation (K.M.K., E-680) are gratefully acknowledged.
Four awl-substituted tripyrrinone copper(II) complexes were synthesized and characterized as to their electro- chemical and spectroelectrochemical properties. The examined compounds are represented as (YPh)3TPO2Cu...
1 Results Energy levels of the metal 3d orbitals in iron(Ⅲ) porphyrinoids are controlled by various factors such as the nature and number of axial ligands, electronic and steric effects of peripheral substituents, de...