Pd-catalyzed functionalization of 1,3-enynes via alkylene-π-allylpalladium intermediates  

作　　者：Long Li Shan Wang Ajay Jakhar Zhihui Shao 

机构地区：[1]State Key Laboratory for Conservation and Utilization of Bio-Resources in Yunnan,School of Life Sciences,Yunnan University,Kunming 650091,China [2]Key Laboratory of Medicinal Chemistry for Natural Resource,Ministry of Education,School of Chemical Science and Technology,Yunnan Provincial Center for Research&Development of Natural Products,Yunnan University,Kunming 650091,China

出　　处：《Green Synthesis and Catalysis》2023年第2期124-134,共11页绿色合成与催化（英文）

基　　金：supported by the National Natural Science Foundation of China(Nos.22171240 and 21861042);the Program for Changjiang Scholars and Innovative Research Team in University(No.IRT17R94);China Postdoctoral Science Foundation(No.2020M712707)。

摘　　要：In recent years,the concept of transition metal-catalyzed functionalization of unsaturated hydrocarbons has emerged as a promising strategy for developing new and valuable reactions,and has attracted considerable attention because it is efficient and atomic economical.In this critical review,we describe recent advances that have been made in the development of transition metal-catalyzed functionalization of 1,3-enynes via alkyleneπ-allylpalladium intermediates.

关 键 词：PALLADIUM-CATALYZED 1 3-Enynes Alkylidene-π-allylpalladium intermediates 

分 类 号：O643.3[理学—物理化学]