花岗岩废料与玻璃废渣制备发泡陶瓷的研究  

Preparation of Foamed Ceramics from Granite Waste and Glass Waste Residue

作　　者：赵成琳 袁文海 董祎然 姜葱葱[1] 何彪 黄世峰[1] 程新[1] ZHAO Chenglin;YUAN Wenhai;DONG Yiran;JIANG Congcong;HE Biao;HUANG Shifeng;CHENG Xin(Shandong Provincial Key Laboratory of Preparation and Measurement of Building Materials,University of Jinan,Jinan 250022,China;Chongqing Three Primary Colors Energy-saving Construction Engineering Co.,Ltd.,Chongqing 401120,China;Shandong Provincial Academy of Architectural Science Co.,Ltd.,Jinan 250031,China)

机构地区：[1]济南大学建筑材料制备与测试技术重点实验室,济南250022 [2]重庆三原色节能建筑工程有限公司,重庆401120 [3]山东省建筑科学研究院有限公司,济南250031

出　　处：《硅酸盐通报》2024年第1期329-338,共10页Bulletin of the Chinese Ceramic Society

基　　金：国家自然科学基金(52202021);济南大学科技计划(XBS2203)。

摘　　要：本文以花岗岩废料和玻璃废渣为原料、SiC为发泡剂,采用粉末烧结法制备了高孔隙率、低吸水率的全固废发泡陶瓷,探究了花岗岩废料和玻璃废渣配合比、烧结温度、发泡剂掺量对发泡陶瓷孔结构及性能的影响。结果表明:花岗岩废料形成了发泡陶瓷的骨架结构,玻璃废渣具有助熔作用;当玻璃废渣掺量为20%(质量分数)时,烧结温度降低了40℃。在1110~1150℃下制备的发泡陶瓷抗压强度为2.23~0.41 MPa,体积密度为468.41~326.31 kg/m^(3),孔隙率为79.15%~86.81%,吸水率为0.96%~1.00%,平均孔径为0.49~1.43 mm,实现了对发泡陶瓷孔径的有效调控,满足了不同应用场景对发泡陶瓷不同孔径的需求。本研究为花岗岩废料和玻璃废渣的规模化利用及不同孔径发泡陶瓷的制备提供了技术支持。In this paper,all-solid waste foamed ceramics with high porosity and low water absorption were prepared by powder sintering method,using granite waste and glass waste residue as raw materials and SiC as foaming agent.The effects of mix ratio of granite waste and glass waste residue,sintering temperature,and foaming agent content on pore structure and properties of foamed ceramics were explored.The results show that granite waste forms a framework structure of foamed ceramics,while glass waste residue has a melting aid effect.When glass waste residue content is 20%(mass fraction),the sintering temperature decreases by 40℃.The compressive strength of foamed ceramics prepared at 1110~1150℃ is 2.23~0.41 MPa,the bulk density is 468.41~326.31 kg/m^(3),the porosity is 79.15%~86.81%,the water absorption rate is 0.96%~1.00% and the average pore size is 0.49~1.43 mm,which effectively regulates the pore size of foamed ceramics and meets the needs of different application scenarios for different pore sizes of foamed ceramics.This study provides technical support for the large-scale utilization of granite waste and glass waste residue,as well as the preparation of foamed ceramics with different pore sizes.

关 键 词：发泡陶瓷 花岗岩废料 玻璃废渣 固废利用 孔结构 碳化硅 

分 类 号：TQ174[化学工程—陶瓷工业]