具有三光子性质的碘代咔唑基三吡啶锰(Ⅱ)配合物的合成及光动力学活性  

Synthesis and photodynamic activity of iodocarbazolyl Manganese tripyridine(Ⅱ)complexes with three-Photon properties

作　　者：张琼[1] 李雅琴 刘玲玲 蔡昌婷 乔瑞 宣俊 ZHANG Qiong;LI Yaqin;LIU Lingling;CAI Changting;QIAO Rui;XUAN Jun(College of Chemistry&Chemical Engineering,Key Laboratory of Functional Inorganic Material Chemistry of Anhui Province,Anhui University,Hefei Anhui 230601,China;School of Chemistry and Materials Engineering,Fuyang Normal University,FuyangAnhui236037,China)

机构地区：[1]安徽大学化学化工学院,功能无机材料化学安徽省重点实验室,安徽合肥230601 [2]阜阳师范大学化学与材料工程学院,安徽阜阳236037

出　　处：《阜阳师范大学学报（自然科学版）》2023年第4期56-60,共5页Journal of Fuyang Normal University:Natural Science

基　　金：安徽省自然科学基金(2008085QB52)资助。

摘　　要：论文以三联吡啶为主体,设计合成碘代咔唑基三吡啶锰(Ⅱ)配合物MB3。MB3具有优良的光电性能,且价格低廉、毒性小。光物理测试表明MB3具有较强的三光子吸收性质。生物测试表明MB3具有良好的单线态氧生成效率,具有作为光敏剂的潜力。The paper focuses on the design and synthesis of a manganese(Ⅱ)complex,MB3,based on tridentate pyridine ligands with carbazole moieties.MB3 exhibits excellent photoelectric properties and possesses the advantages of being cost-effective and low in toxicity.Photophysical testing demonstrates that MB3 possesses strong three-photon absorption properties.Biological testing reveals that MB3 exhibits a high singlet oxygen generation efficiency,indicating its potential as a photosensitizer.

关 键 词：锰配合物 三光子吸收 ROS 光敏剂 

分 类 号：O622.6[理学—有机化学]