氨硼烷催化水解制氢综合实验设计  

Comprehensive Experiment Design of Hydrogen Production by Catalytic Hydrolysis of Aminoborane

作　　者：武美霞[1] 杨肖萌 王俊丽[1] 张三兵[2] 李作鹏[1] WU Meixia;YANG Xiaomeng;WANG Junli;ZHANG Sanbing;LI Zuopeng(School of Chemistry and Chemical Engineering,Shanxi Datong University,Datong 037009,Shaanxi,China;Department of Applied Chemistry,College of Sciences,China Agricultural University,Beijing 100193,China)

机构地区：[1]山西大同大学化学与化工学院,山西大同037009 [2]中国农业大学理学院应用化学系,北京100193

出　　处：《实验室研究与探索》2024年第1期147-151,共5页Research and Exploration In Laboratory

基　　金：国家自然科学基金项目(21908135);教育部产学合作协同育人项目(220506537290739);山西省一流课程建设项目(K2021163);山西省高等学校精品共享课程(K2020411);山西省研究生教育教学改革课题(2022YJJG255);大同大学研究生教育教学改革课题(22JG06)。

摘　　要：根据物理化学实验教学的需求,设计了氨硼烷催化水解制氢综合探索性实验。采用化学还原法制备了新型镍硼纳米催化剂,将其用于氨硼烷水解催化反应,考察催化剂用量和温度对反应速率的影响,并根据阿雷尼乌斯公式测定反应的活化能。通过探索性操作完成整个实验流程,学生不仅可以掌握催化剂的化学还原法制备技术,还可以强化和巩固利用化学动力学知识分析处理实验数据的能力。In order to satisfy the needs of physical chemistry experiment teaching,a comprehensive exploratory experiment of hydrogen production by catalytic hydrolysis of aminoborane is designed based on the scientific hot spots and the authors’research field.A new type of nickel-boron nano-catalyst is prepared by chemical reduction method and used in the catalytic reaction of aminoborane hydrolysis.The effect of catalyst dosage and temperature on the reaction rate is investigated.The activation energy of the reaction is determined according to Arrhenius formula.Through exploratory operation and completion of the whole experimental process,students can not only master the chemical reduction preparation technology of catalysts,but also strengthen and consolidate the ability to analyze and process experimental data using chemical kinetic knowledge.

关 键 词：氨硼烷 储氢材料 制氢 实验教学 

分 类 号：O643.36[理学—物理化学]