基于斜塔芳烃的晶体工程研究  

Crystal Engineering Based on Leaning Towerarenes

作　　者：吴佳睿 吴庚辛 王艳[1] 杨英威[1] Jiarui Wu;Gengxin Wu;Yan Wang;Yingwei Yang(College of Chemistry,Jilin University,Changchun 130012,China)

机构地区：[1]吉林大学化学学院,长春130012

出　　处：《大学化学》2024年第3期58-62,共5页University Chemistry

基　　金：国家自然科学基金青年项目(22201096);国家自然科学基金面上项目(52173200);中国博士后科学基金博新计划项目(BX2021112)。

摘　　要：凭借固有的分子识别和络合能力,大环主体分子一直是超分子化学研究所依赖的重要工具,同时也大力地推动了现代超分子化学的蓬勃发展并从基础研究走向实际应用。斜塔芳烃做为一类新型芳烃大环受体具有易溶解、易结晶、良好的骨架柔性和主客体化学性质等特点和优势,自其诞生以来便在晶体工程和相关研究领域得到广泛应用和发展。本文将从晶体工程角度出发来介绍若干有关斜塔芳烃的应用研究实例,重点突出结构与功能之间的内在关联,以期提高学生对晶体化学及其交叉学科的学习兴趣和内在驱动力。Macrocyclic receptors have served as the principal tools of supramolecular chemistry because of their innate molecular recognition and complexation capabilities.They have also increased research interest in modern supramolecular chemistry because of their practical applications.Leaning towerarenes,a new family of synthetic macrocycles,have various applications in crystal engineering and other related fields owing to their excellent solubility and crystallization,flexible backbone,and superior host-guest properties.In this paper,we summarize the applications of leaning towerarenes from the perspective of crystal engineering.Particular attention is paid to the correlation between their structural features and supramolecular functions.We hope this will stimulate students’interest in crystal chemistry and beyond.

关 键 词：晶体工程 超分子化学 大环化学 主客体化学 

分 类 号：G64[文化科学—高等教育学] O6[文化科学—教育学]