利用双金属接力催化策略合成环状有机化合物研究进展  

Research Progress in the Synthesis of Cyclic Organic Compounds Using Bimetallic Relay Catalytic Strategies

作　　者：许珈铭 向羽 林维晟 苗志伟[1] Jiaming Xu;Yu Xiang;Weisheng Lin;Zhiwei Miao(State Key Laboratory and Institute of Elemento-Organic Chemistry,College of Chemistry,Nankai University,Tianjin 300071,China;Department of Ecological and Resources Engineering,Wuyi University,Wuyishan 354300,Fujian Province,China)

机构地区：[1]南开大学化学学院,元素有机化学国家重点实验室,天津300071 [2]武夷学院生态与资源工程学院,福建武夷山354300

出　　处：《大学化学》2024年第3期239-257,共19页University Chemistry

基　　金：国家自然科学基金面上项目(22071113);福建省南平市科技项目(N2020Z008)。

摘　　要：环状有机化合物在有机化学、药物化学和材料科学领域具有广泛应用,过渡金属催化的成环反应是制备多种环状化合物的有效方法之一。近年来科学家在研究单一过渡金属催化成环反应体系的基础上,进一步开发了金属/金属组合的接力催化体系,双金属接力催化体系因其可以促进单一金属催化体系无法实现的转化而受到了极大的关注。本文综述了近五年来利用双金属接力催化策略实现环状有机化合物合成的研究进展,并对该领域的发展前景进行了展望。Cyclic organic compounds play a crucial role in organic chemistry,pharmaceutical chemistry,and materials science.Among the various methods for constructing these compounds,metal-catalyzed cycloaddition and cyclization reactions stand out as powerful approaches.In recent years,scientists have made significant advancements by developing bimetallic relay catalytic systems based on the study of single-transition-metal catalytic cyclization reactions.These bimetallic relay catalytic systems have garnered immense attention due to their ability to facilitate transformations that are unattainable through individual catalytic systems alone.This paper provides a comprehensive review of the recent progress made in the synthesis of cyclic compounds through bimetallic relay catalysis over the past five years,while also offering insights into the future directions of this exciting field.

关 键 词：双金属接力催化 环状化合物 合成 

分 类 号：G64[文化科学—高等教育学] O6[文化科学—教育学]