Recent Progress of Asymmetric Catalysis from a Chinese Perspective  

作　　者：Yan-Mei He Yuan-Zheng Cheng Yingdong Duan Yan-Dong Zhang Qing-Hua Fan Shu-Li You Sanzhong Luo Shou-Fei Zhu Xue-Feng Fu Qi-Lin Zhou 

机构地区：[1]Beijing National Laboratory for Molecular Sciences,Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190 [2]State Key Laboratory of Organometallic Chemistry,Shanghai Institute of Organic Chemistry,Chinese Academy of Sciences,Shanghai 200032 [3]Center of Basic Molecular Science,Department of Chemistry,Tsinghua University,Beijing 100084 [4]State Key Laboratory and Institute of Elemento-Organic Chemistry,College of Chemistry,Nankai University,Tianjin 300071 [5]Department of Chemical Sciences,National Natural Science Foundation of China,Beijing 100085

出　　处：《CCS Chemistry》2023年第12期2685-2716,共32页中国化学会会刊（英文）

基　　金：supported by major research plan“Precise Construction of Multilevel Chiral Substances”of the National Natural Science Foundation of China(grant nos.91956000,92256000,and 92256303).

摘　　要：The precise construction of chiral molecules is a core research area in chemical science and technology.Among the plethora of reported synthetic methods,asymmetric catalysis has emerged as one of the most efficient and direct ways to obtain optically pure chiral compounds.This article mainly reviews the recent progress of asymmetric catalysis made by Chinese chemists from the following aspects:the development of new chiral ligands,transition metal-catalyzed asymmetric reactions,asymmetric organocatalytic reactions,and new strategies for asymmetric catalysis.This review does not intend to be comprehensive;only representative examples are selected to highlight the important progress made in this field.Finally,a brief outlook is given on the development of novel chiral ligands/catalysts,new enantioselective reactions,and their applications in chiral drugs and agricultural chemicals.

关 键 词：asymmetric catalysis chiral ligands ORGANOCATALYSTS enantioselective reactions cooperative catalysis 

分 类 号：O62[理学—有机化学]