ORGANOCATALYSTS

作品数:21被引量:33H指数:3
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相关领域:理学更多>>
相关期刊:《Science China Chemistry》《Chemical Research in Chinese Universities》《Chinese Journal of Polymer Science》《合成化学》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划国家教育部博士点基金中国博士后科学基金更多>>
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The chlorine evolution reaction promoted by organocatalysts with amide functional groups
《Science China Chemistry》2024年第3期749-750,共2页Lan Zhao Liang-Nian He 
Since the nineteenth century, the chlor-alkali process entails the electrochemical oxidation of sodium chloride solutions to Cl_(2) by the chlorine evolution reaction(CER) and the simultaneous production of sodium hyd...
关键词:CHLORINE HYDROXIDE promoted 
Recent Progress of Asymmetric Catalysis from a Chinese Perspective被引量:4
《CCS Chemistry》2023年第12期2685-2716,共32页Yan-Mei He Yuan-Zheng Cheng Yingdong Duan Yan-Dong Zhang Qing-Hua Fan Shu-Li You Sanzhong Luo Shou-Fei Zhu Xue-Feng Fu Qi-Lin Zhou 
supported by major research plan“Precise Construction of Multilevel Chiral Substances”of the National Natural Science Foundation of China(grant nos.91956000,92256000,and 92256303).
The precise construction of chiral molecules is a core research area in chemical science and technology.Among the plethora of reported synthetic methods,asymmetric catalysis has emerged as one of the most efficient an...
关键词:asymmetric catalysis chiral ligands ORGANOCATALYSTS enantioselective reactions cooperative catalysis 
Stereoselective Ring-Opening Polymerization of rac-Lactide Catalyzed by Squaramide Derived Organocatalysts at Room Temperature被引量:1
《Chinese Journal of Chemistry》2021年第9期2403-2409,共7页Xiao Jiang Na Zhao Zhibo Li 
Financial support received from NSFC(Nos.21704048,22031005);the Department of Science and Technology of Shandong Province(No.ZR2020LFG014);the Taishan Scholars Constructive Engineering Foundation(No.tsqn20161031)is gratefully acknowledged.
Substa ntial progresses have bee n made toward the developme nt of meta I-free catalysts for stereoselective rin g-ope ning polymeriza-tion(ROP)of rac-lactide.Yet the discovery of organic catalysts effective at ambien...
关键词:Ring-opening polymerization ORGANOCATALYSIS SQUARAMIDE Polymers STEREOSELECTIVE 
Isoselective Ring-opening Polymerization of Racemic Lactide Catalyzed by N-heterocyclic Olefin/(Thio)urea Organocatalysts被引量:1
《Chinese Journal of Polymer Science》2021年第6期709-715,I0006,共8页Zhen-Yu Wang Guang-Qiang Xu Li Zhou Cheng-Dong Lv Ru-Lin Yang Bing-Zhe Dong Qing-Gang Wang 
by the National Key R&D Plan(No.2017YFC1104800);the National Natural Science Foundation of China(Nos.21901249 and 21950410529);Taishan Scholars Program of Shandong Province(No.tsqn201812112);“135”Projects Fund of CAS-QIBEBT Director Innovation Foundation and DICP&QIBEBT United Foundation(No.UN201701).
The isoselective ring-opening polymerization of racemic lactide was achieved by combining N-heterocyclic olefin(NHO)with mono(thio)ureas or bis(thio)ureas as catalytic systems.The polymerization process shows high ste...
关键词:mechanism. HETEROCYCLIC polymerization 
Recent advances towards catalytic asymmetric Conia-ene-type reactions被引量:1
《Chinese Chemical Letters》2021年第3期954-962,共9页En-Ze Lin Yin Xu Kegong Ji Long-Wu Ye 
financial support from the National Natural Science Foundation of China(Nos.2170217,21772161);the Natural Science Foundation of Fujian Province of China(No.2019J02001);Natural Science Foundation of Shaanxi(No.2018JQ2072);the Youth Training Program of Northwest A&F University(No.2452016006);the President Research Funds from Xiamen University(No.20720180036),PCSIRT;Science&Technology Cooperation Program of Xiamen(No.3502Z20183015)。
Conia-ene reactions,as a type of ene reactions,have not become a remarkable focus until the beginning of21st century,when Lewis acids served as powerful catalysts and found an increasingly broad utilization in this fi...
关键词:Conia-ene reaction Asymmetric catalysis Transition metals ORGANOCATALYSTS 
Heterogeneous catalysts with programmable topologies generated by reticulation of organocatalysts into metal-organic frameworks:The case of squaramide被引量:1
《Nano Research》2021年第2期458-465,共8页Anna Broto-Ribas Claudia Vignatti Alicia Jimenez-Almarza Javier Luis-Barrera Zahra Dolatkhah Felipe Gandara Inhar Imaz Ruben Mas-Balleste Jose Aleman Daniel Maspoch 
the Spanish MINECO(projects RTI2018-095622-B-I00,RTI2018-095038-B-I00);the Catalan AGAUR(project 2017 SGR 238);the ERC under the EU FP7(ER C-Co 615954);European Unions Horizon 2020 research and innovation program under grant agreement No.685727,and European Structural Funds(S2018/NMT-4367).It was alsofunded by the CERCA Program/Generalitat de Catalunya.ICN2 is supported by the Severo Ochoa program from the Spanish MINECO(G rant No.SEV-2017-0706).
A well-established strategy to synthesize heterogeneous,metal-organic framework(MOF)catalysts that exhibit nanoconfinement effects,and specific pores with highly-localized catalytic sites,is to use organic linkers con...
关键词:reticular chemistry metal-organic frameworks H-bond catalysis SQUARAMIDE Friedel-Cratts epoxide ring-opening 
Dual cooperative organocatalysts for one-pot synthesis of polyester-polythiocarbonate block copolymers from multiple monomers
《Science China Chemistry》2020年第12期1807-1814,共8页Cheng-Jian Zhang Xun Zhang Xing-Hong Zhang 
This work was supported by the National Natural Science Foundation of China(51973190,21774108).
The sequential arrangement of multiple monomer units in a polymer chain remains a major challenge in synthetic chemistry.Here we describe a versatile route to the novel polyester-polythiocarbonate block copolymer from...
关键词:block copolymer POLYESTER polythiocarbonate ORGANOCATALYSIS polymer synthesis 
Readily Prepared and Tunable Ionic Organocatalysts for Ring-opening Polymerization of Lactones被引量:3
《Chinese Journal of Polymer Science》2019年第12期1205-1214,I0005,共11页Zhuo-Lun Jiang Jun-Peng Zhao Guang-Zhao Zhang 
financially supported by the National Natural Science Foundation of China (Nos. 21734004 and 21674038)
Highly potent ionic organocatalyst is developed for room-temperature controlled ring-opening polymerization(ROP)of lactones,includingδ-valerolactone,ε-caprolactone,andδ-hexalactone.The catalysts are prepared by sim...
关键词:Organocatalytic POLYMERIZATION RING-OPENING POLYMERIZATION POLYESTER 
Chiral Amino Acids-Derived Catalysts and Ligands被引量:9
《Chinese Journal of Chemistry》2018年第9期791-797,共7页Xiaohua Liu Shunxi Dong Lili Lin Xiaoming Feng 
Transforming amino acids into novel catalysts and ligands is a remarkable subset of new catalyst development in order to imitate enzymatic efficiencies. Their ability to perform a variety of asymmetric catalytic react...
关键词:CHIRALITY asymmetric catalysis amino acids ORGANOCATALYSTS LIGANDS 
Lewis base-CO2 adducts as organocatalysts for CO2 transformation被引量:2
《Science China Chemistry》2017年第7期904-911,共8页Hui Zhou Xiaobing Lu 
supported by the National Natural Science Foundation of China(21402021);the Program for Changjiang Scholars and Innovative Research Team in University(IRT13008)
In the recent decade, the development and application of organocatalysis for CO_2 transformation into useful chemicals have attracted much attention. Among these organocatalysts, Lewis base-CO_2 adducts(LB-CO_2) were ...
关键词:Lewis base CO2 adduct organocatalyst CO2 transformation cyclic carbonate 
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