Since the nineteenth century, the chlor-alkali process entails the electrochemical oxidation of sodium chloride solutions to Cl_(2) by the chlorine evolution reaction(CER) and the simultaneous production of sodium hyd...
supported by major research plan“Precise Construction of Multilevel Chiral Substances”of the National Natural Science Foundation of China(grant nos.91956000,92256000,and 92256303).
The precise construction of chiral molecules is a core research area in chemical science and technology.Among the plethora of reported synthetic methods,asymmetric catalysis has emerged as one of the most efficient an...
Financial support received from NSFC(Nos.21704048,22031005);the Department of Science and Technology of Shandong Province(No.ZR2020LFG014);the Taishan Scholars Constructive Engineering Foundation(No.tsqn20161031)is gratefully acknowledged.
Substa ntial progresses have bee n made toward the developme nt of meta I-free catalysts for stereoselective rin g-ope ning polymeriza-tion(ROP)of rac-lactide.Yet the discovery of organic catalysts effective at ambien...
by the National Key R&D Plan(No.2017YFC1104800);the National Natural Science Foundation of China(Nos.21901249 and 21950410529);Taishan Scholars Program of Shandong Province(No.tsqn201812112);“135”Projects Fund of CAS-QIBEBT Director Innovation Foundation and DICP&QIBEBT United Foundation(No.UN201701).
The isoselective ring-opening polymerization of racemic lactide was achieved by combining N-heterocyclic olefin(NHO)with mono(thio)ureas or bis(thio)ureas as catalytic systems.The polymerization process shows high ste...
financial support from the National Natural Science Foundation of China(Nos.2170217,21772161);the Natural Science Foundation of Fujian Province of China(No.2019J02001);Natural Science Foundation of Shaanxi(No.2018JQ2072);the Youth Training Program of Northwest A&F University(No.2452016006);the President Research Funds from Xiamen University(No.20720180036),PCSIRT;Science&Technology Cooperation Program of Xiamen(No.3502Z20183015)。
Conia-ene reactions,as a type of ene reactions,have not become a remarkable focus until the beginning of21st century,when Lewis acids served as powerful catalysts and found an increasingly broad utilization in this fi...
the Spanish MINECO(projects RTI2018-095622-B-I00,RTI2018-095038-B-I00);the Catalan AGAUR(project 2017 SGR 238);the ERC under the EU FP7(ER C-Co 615954);European Unions Horizon 2020 research and innovation program under grant agreement No.685727,and European Structural Funds(S2018/NMT-4367).It was alsofunded by the CERCA Program/Generalitat de Catalunya.ICN2 is supported by the Severo Ochoa program from the Spanish MINECO(G rant No.SEV-2017-0706).
A well-established strategy to synthesize heterogeneous,metal-organic framework(MOF)catalysts that exhibit nanoconfinement effects,and specific pores with highly-localized catalytic sites,is to use organic linkers con...
This work was supported by the National Natural Science Foundation of China(51973190,21774108).
The sequential arrangement of multiple monomer units in a polymer chain remains a major challenge in synthetic chemistry.Here we describe a versatile route to the novel polyester-polythiocarbonate block copolymer from...
financially supported by the National Natural Science Foundation of China (Nos. 21734004 and 21674038)
Highly potent ionic organocatalyst is developed for room-temperature controlled ring-opening polymerization(ROP)of lactones,includingδ-valerolactone,ε-caprolactone,andδ-hexalactone.The catalysts are prepared by sim...
Transforming amino acids into novel catalysts and ligands is a remarkable subset of new catalyst development in order to imitate enzymatic efficiencies. Their ability to perform a variety of asymmetric catalytic react...
supported by the National Natural Science Foundation of China(21402021);the Program for Changjiang Scholars and Innovative Research Team in University(IRT13008)
In the recent decade, the development and application of organocatalysis for CO_2 transformation into useful chemicals have attracted much attention. Among these organocatalysts, Lewis base-CO_2 adducts(LB-CO_2) were ...