纳米颗粒修饰的PVB复合涂膜合成及其抑菌抗病毒性能  

Preparation of PVB composite coating films with nanoparticle modification for antibacterial and antiviral application

作　　者：谢志豪 陆钢[1] 龙兴虎 蒋利 龙楚锜 刘海[1] XIE Zhihao;LU Gang;LONG Xinghu;JIANG Li;LONG Chuqi;LIU Hai(College of Environment and Climate,Jinan University,Guangzhou 511443,Guangdong,China;Yunguang Technology(Shenzhen)Co.,LTD,Shenzhen 518115,Guangdong,China)

机构地区：[1]暨南大学环境与气候学院,广东广州511443 [2]云广技术(深圳)有限公司,广东深圳518115

出　　处：《暨南大学学报（自然科学与医学版）》2024年第2期201-209,共9页Journal of Jinan University(Natural Science & Medicine Edition)

基　　金：国家自然科学基金项目(22206058);云广技术(深圳)有限公司横向项目(ZX20230646)。

摘　　要：目的:制备一种可涂覆于材料表面、具有抑菌抗病毒性能的涂膜,旨在应用于多种公共场所设施表面以控制病原微生物的传播。方法:以无毒易挥发的乙醇溶解聚乙烯醇缩丁醛(PVB)树脂材料,通过掺杂具有抑菌抗病毒性能的纳米氧化锌(ZnONP)或纳米氧化铜(CuONP)颗粒,制备具有抑菌抗病毒性能的涂膜材料,并研究纳米颗粒种类、粒径、掺杂量对涂膜消毒性能的影响。结果:扫描电镜表征结果表明CuONP和ZnONP可与PVB形成稳定涂膜,且该涂膜的接触面积越大、纳米颗粒掺杂量越高,对大肠杆菌、MS2噬菌体的灭活效果越好。接触面积大于80 cm^(2)时灭活率可达90%,且去除速率大于1%/min。结论:PVB复合涂膜具有高效的抑菌抗病毒活性,可为公共卫生消毒提供新手段。Objective:Coating films were fabricated with antibacterial and antiviral activity,which can be widely used on surfaces of public facilities to control the microbiological risk.Methods:The resin polyvinyl butyral(PVB)was dissolved in non-toxic and volatile ethanol,and then nano-zinc oxide(ZnONP)or nano-copper oxide(CuONP)particles with antibacterial and antiviral effects were added.The disinfection performance of the coating films was investigated via adding nanoparticles with different sizes and amounts.Results:Analyses of scanning electron microscopy showed that CuONP and ZnONP formed uniform films with PVB.In addition,the larger contact area and the higher dosage of nanoparticles promoted the bactericidal effect against E.coli and MS2 phage.With the contact area larger than 80 cm^(2),the removal can reach up to 90%with removal rate over 1%/min.Conclusion:The PVB composite coating films have high antibacterial and antiviral activity,which provides a new approach to control microbiological risk for public health.

关 键 词：抑菌抗病毒 纳米材料 涂膜 消毒 

分 类 号：R126.4[医药卫生—环境卫生学]