ε-聚赖氨酸盐酸盐接枝淀粉薄膜的制备及性质研究  

Preparation and Characterization ofε-polylysine-HCl Grafted Starch-based Antimicrobial Films

作　　者：刘勇 马文雅[1] 刘孝芳 陈霄汉 李立 LIU Yong;MA Wenya;LIU Xiaofang;CHEN Xiaohan;LI Li(College of Food Science and Technology,Shanghai Ocean University,Shanghai 201306,China;Engineering Research Center of Food Thermal-Processing Technology,Shanghai Ocean University,Shanghai 201306,China)

机构地区：[1]上海海洋大学食品学院,上海201306 [2]上海海洋大学食品热加工工程技术研究中心,上海201306

出　　处：《包装工程》2024年第13期35-41,共7页Packaging Engineering

基　　金：上海市科技创新行动计划(23N31900200)。

摘　　要：目的对淀粉接枝抑菌肽,得到抑菌淀粉,并挤出成膜,表征其性质,为淀粉的应用提供参考。方法借助偶联剂,将ε-聚赖氨酸盐酸盐(ε-polylysine-HCl,ε-PLH)接枝到玉米淀粉上,分析其化学结构、微观结构、热性能及抑菌性。通过熔融挤出法将接枝淀粉与聚乳酸(Polylactic acid,PLA)、聚己二酸/对苯二甲酸丁二酯(Poly butyleneadipate-co-terephthalate,PBAT)共混改性成膜,表征其力学性能、抑菌性能。结果FTIR显示,ε-PLH被成功接枝到淀粉分子上;热重分析(TGA)结果显示,接枝淀粉的起始分解温度有所下降;含有30%接枝淀粉的PBAT/PLA薄膜具有更高的拉伸强度。此外,接枝淀粉添加量为30%的薄膜对大肠杆菌、金黄色葡萄球菌的抑制率分别达到了46.53%、68.81%。结论接枝ε-聚赖氨酸盐酸盐是一种有效的淀粉改性途径,接枝淀粉/PBAT/PLA薄膜具有良好的应用前景。The work aims to graftε-polylysine-HCl(ε-PLH)onto corn starch so as to prepare antimicrobial starch,and prepare films based the grafted starch and characterize the properties of both grafted starch and films to provide reference for application of starch.Coupling agent was utilized to graft starch andε-PLH and the chemical structure,micromorphology,thermal stability and antimicrobial properties of grafted starch were determined.Films were prepared by the modified starch,polylactic acid(PLA)and poly(butylene adipate co-terephthalate)(PBAT)through melt extrusion process.The mechanical and antimicrobial properties of films were determined.FTIR results showed thatε-PLH was grafted onto starch successfully,and thermogravimetric analysis(TGA)showed decrease in the initial decomposition temperature of grafted starch.The films with 30%grafted starch presented better tensile strength.Moreover,the films with 30%grafted starch showed 46.53%and 68.81%inhibitory rate against E.coli and S.aureus respectively.In conclusion,graftingε-PLH is an approach that effectively modifies starch and the grafted starch/PBAT/PLA films have great practical potential.

关 键 词：玉米淀粉 ε-聚赖氨酸盐酸盐 接枝 改性 淀粉膜 

分 类 号：TB484.9[一般工业技术—包装工程]