含磷废水的处理及排放评价  

Treatment and Discharge Evaluation of Phosphorus-Containing Wastewater

作　　者：王静[1] 李平平 王玥辉 修一凡 张秉乾 王书文[1] 高洪涛[1] Jing Wang;Pingping Li;Yuehui Wang;Yifan Xiu;Bingqian Zhang;Shuwen Wang;Hongtao Gao(College of Chemistry and Molecular Engineering,Qingdao University of Science and Technology,Qingdao 266042,Shandong Province,China;College of Materials Science and Engineering,Qingdao University of Science and Technology,Qingdao 266042,Shandong Province,China)

机构地区：[1]青岛科技大学化学与分子工程学院,山东青岛266042 [2]青岛科技大学材料科学与工程学院,山东青岛266042

出　　处：《大学化学》2024年第5期52-62,共11页University Chemistry

基　　金：2021年第二批山东省一流本科课程(鲁教高函[2021]24号);山东省本科教学改革研究项目重点项目(Z2021020);山东省智慧教育研究重点项目(鲁教馆函[2023]15号);青岛科技大学第三批“课程思政”教育教学改革试点课程(2021szjglx06);青岛科技大学2022年教学改革研究项目重点项目(2022ZD004,2022ZD047)。

摘　　要：对分析化学实验“分光光度法测定水和废水中总磷”进行改进:以绿色无毒的麦饭石为载体,制备ZnFe-LDHs(层状双金属氢氧化物)改性麦饭石吸附材料,运用FTIR、XRD、SEM、EDS-mapping等手段进行表征,探索出ZnFeLDHs改性麦饭石对磷的最优吸附处理条件,去除率大于98.4%。含磷废水经改性麦饭石吸附处理后,磷的浓度小于0.08 mg·L^(-1),符合磷一级排放标准。该改进实验内容丰富,综合性强,学生在践行“绿色化学”理念中,综合研究能力和团队协作能力得到培养提升,适合推广至本科生高年级教学。This study presents an improvement to the analytical chemistry experiment“Determination of total phosphorus in water and wastewater by spectrophotometry”.Maifannite,a green and non-toxic material,was modified with ZnFe-LDHs(layered double hydroxides)to create an adsorption material.The modified Maifannite was characterized using FTIR(Fourier Transform Infrared Spectroscopy),XRD(X-ray Diffraction),SEM(Scanning Electron Microscope),and EDS-mapping(Energy Dispersive X-ray Spectroscopy Mapping).Optimal adsorption conditions for total phosphorus by ZnFe-LDHs modified Maifannite were explored,achieving a removal rate of over 98.4%.After treatment with modified Maifannite,the concentration of phosphorus in wastewater was reduced to less than 0.08 mg·L^(−1),meeting the first-level discharge standard for phosphorus.This enhanced experiment is rich in content,comprehensive,and cultivates students’research and teamwork abilities while practicing the concept of“green chemistry”.It is suitable for extension to higher-grade undergraduate teaching.

关 键 词：改性麦饭石 吸附 磷含量测定 环境友好 创新设计与改进 

分 类 号：G64[文化科学—高等教育学] O6[文化科学—教育学]