水体中天然有机物与新污染物的相互作用及环境影响研究进展  

A Review of the Interaction of Natural Organic Matter and Contaminants of Emerging Concern in Water and Its Environmental Impact

作　　者：何歆逸 姚倩倩 焦伟 姚志建 HE Xin-yi;YAO Qian-qian;JIAO Wei;YAO Zhi-jian(State Key Laboratory of Pollution Control and Resource Reuse,School of the Environment,Nanjing University,Nanjing 210023,China;Jiangsu Guochuang Environmental Protection Technology Co.,Ltd.,Nanjing 211046,China)

机构地区：[1]污染控制与资源化研究国家重点实验室,南京大学环境学院,江苏南京210023 [2]江苏国创环保科技有限公司,江苏南京211046

出　　处：《环境科技》2024年第4期65-69,74,共6页Environmental Science and Technology

基　　金：国家自然科学基金面上项目(52070093);江苏省杰出青年基金项目(BK20211509),。

摘　　要：环境水体中的天然有机物(NOM)会与部分新污染物(CECs)发生相互作用,影响后者的定量检测、迁移转化及最终的降解去除。以荧光光谱法为代表的定量研究方法和机制表征手段为NOM与CECs结合作用的研究奠定了基础。NOM与CECs的结合机制包括疏水作用和与极性基团相关的特异性作用,结合强弱与两者的性质、浓度和环境条件相关。NOM可作为反应物、引发剂和促进剂促进CECs的自然与化学降解过程。在絮凝、吸附和膜滤工艺中,特定浓度的NOM可为CECs提供额外的吸附作用点位,促进CECs的去除。The presence of natural organic matter(NOM)can interact with certain contaminants of emerging concern(CECs)in water,affecting their detection,migration,transformation and degradation.The quantitative research methods and mechanism characterization methods represented by fluorescence spectroscopy have laid a foundation for the study of the binding effect of NOM and CECs.The binding mechanism of NOM and CECs includes hydrophobic effects and specific effects related to polar groups on NOM.The intensity of binding is related to the intrinsic properties,concentrations,and prevailing environmental conditions both of NOM and CECs.NOM can be used as a reactant,initiator and accelerator to promote the natural and chemical degradation of CECs.In treatment processes such as flocculation,adsorption and membrane filtration processes,specific concentrations of NOM can enhance the removal efficiency of CECs by providing additional adsorption sites.

关 键 词：天然有机物 新污染物 相互作用 环境影响 分析方法 

分 类 号：X5[环境科学与工程—环境工程]