氧化锌黄芩苷紫外屏蔽复合材料的制备与研究  

Preparation and study of zinc oxide baicalin ultraviolet shielding composite material

作　　者：余瑶瑶 孙晓敏 吴鑫 蔡悦 左士祥 姚超[1] YU Yao-yao;SUN Xiao-min;WU Xin;CAI Yue;ZUO Shi-xiang;YAO Chao(School of Petrochemical Engineering,Changzhou University,Changzhou 213164,China;Changzhou Nano-materials S&T Co.,Ltd.,Changzhou 213164,China)

机构地区：[1]常州大学石油化工学院,江苏常州213164 [2]常州纳欧新材料科技有限公司,江苏常州213164

出　　处：《现代化工》2024年第9期143-147,154,共6页Modern Chemical Industry

基　　金：常州市科技支撑计划(CE20215031);江苏省重点研发项目(BE2023747)。

摘　　要：将正硅酸乙酯在pH=8~10的条件下水解形成的SiO_(2)包覆于纳米ZnO的表面制备SiO_(2)/ZnO复合材料,以降低纳米ZnO的光活性。将天然药物黄芩苷(BA)包覆在SiO_(2)/ZnO表面制得BA/SiO_(2)/ZnO复合材料,使其兼具紫外屏蔽性能和抗氧化功效。通过Zeta电位、TEM、UV-Vis、FT-IR、TG和XRD等方法对制得的材料进行表征。结果表明,SiO_(2)以Si—O—Zn键的形式结合在纳米ZnO表面,适宜包覆量为20%;药物BA是以无定型的形式包覆在SiO_(2)/ZnO表面,最佳包覆量为20%。抗氧化性实验结果表明,BA/SiO_(2)/ZnO复合材料对DPPH自由基和·OH自由基的清除率与维生素C接近。防晒性能测试结果表明,BA/SiO_(2)/ZnO复合材料具有优异的紫外屏蔽能力。SiO_(2) formed by the hydrolysis of ethyl orthosilicate at pH=8-10 is coated on the surface of ZnO nanoparticles to prepare SiO_(2)/ZnO composites to reduce the photoactivity of ZnO nanoparticles.BA/SiO_(2)/ZnO composites are prepared through coating natural drug baicalin(BA)on the surface of SiO_(2)/ZnO,which gains both UV shielding properties and antioxidant efficacy.The fabricated composites are characterized by means of zeta potential,TEM,UV-Vis,FT-IR,TG and XRD.Results show that SiO_(2) is bonded in the form of Si-O-Zn bonds on the surface of nano ZnO,and the suitable coating amount is 20%.Baicalin,in the form of an amorphous form,is coated on the surface of SiO_(2)/ZnO,and the optimal coating amount is 20%.Antioxidant experiments show that BA/SiO_(2)/ZnO composites have similar scavenging rates for DPPH radical and·OH radical to vitamin C.Sunscreen performance tests show that BA/SiO_(2)/ZnO composites exhibit excellent UV shielding ability.

关 键 词：纳米氧化锌 二氧化硅 黄芩苷 自由基清除能力 防晒指数 

分 类 号：TQ658.24[化学工程—精细化工]