无机白磷(P_(4))活化合成有机磷化合物的研究进展  

Recent Advances in the Synthesis of Organic Phosphorus Compounds via Activation of Inorganic White Phosphorus

作　　者：王丰晓 苗志伟[1] Fengxiao Wang;Zhiwei Miao(State Key Laboratory of Elemento-Organic Chemistry,College of Chemistry,Nankai University,Tianjin 300071,China)

机构地区：[1]南开大学化学学院,元素有机化学国家重点实验室,天津300071

出　　处：《大学化学》2024年第12期185-201,共17页University Chemistry

基　　金：国家自然科学基金面上项目(22071113);福建省南平市科技项目(N2020Z008)。

摘　　要：有机磷化合物在有机化学、农药和材料等领域具有重要应用,白磷(P_(4))是现代磷化工最重要的原料之一,是制备有机磷化合物常见的磷原子源。近年来科研人员一直在研究白磷的化学性质,希望开发出直接将无机白磷转化为含磷功能化合物的方法。从无机白磷出发直接合成有机磷化合物将避开目前磷化工所依赖的多步骤传统工序,在保护环境的同时可以降低生产成本。本文综述了近年来从无机白磷出发直接合成有机磷化合物的研究进展,并对该领域的发展前景进行了展望。Organic phosphorus compounds play a crucial role in various fields,including organic chemistry,agriculture,and materials science.White phosphorus(P_(4))is a key raw material in the modern phosphorus chemical industry and serves as a common source of phosphorus atoms for the synthesis of organic phosphorus compounds.In recent years,researchers have focused on exploring the chemical properties of white phosphorus with the aim of developing methods for the direct conversion of inorganic white phosphorus into phosphorus-containing functional compounds.This approach not only circumvents the multi-step traditional processes currently employed in the phosphorus chemical industry but also contributes to environmental protection and cost reduction.This article reviews the recent advancements in the direct synthesis of organic phosphorus compounds from inorganic white phosphorus and discusses the future prospects for development in this area.

关 键 词：白磷活化 有机磷化合物 直接官能化 

分 类 号：G64[文化科学—高等教育学] O6[文化科学—教育学]