感受氢键魅力:磺酰胺类AIE分子的制备与性质  

Exploring the Charm of Hydrogen Bonding:Synthesis and Properties of Sulfonamide AIE Molecule

作　　者：郭雯霁 曾焱青 劳梓晋 武明涛 高丹丹 李秋莲[1] 龚时琼[1] 罗钒[1] 龚跃法[1] 王龙 Wenji Guo;Yanqing Zeng;Zijin Lao;Mingtao Wu;Dandan Gao;Qiulian Li;Shiqiong Gong;Fan Luo;Yuefa Gong;Long Wang*(School of Chemistry and Chemical Engineering,Huazhong University of Science and Technology,Wuhan 430074,China)

机构地区：[1]华中科技大学化学与化工学院,武汉430074

出　　处：《大学化学》2024年第12期284-291,共8页University Chemistry

基　　金：国家自然科学基金(NSFC21901079);华中科技大学自主创新基金(2019kfyXJJS069)。

摘　　要：氢键在化学和生命科学中意义重大,聚集诱导发光(AIE)是有机化学和材料科学的前沿科研方向,开展相关的教学实验有助于学生创新能力的培养。本文设计了一个教学实验,将基础有机化学中的缩合反应和兴斯堡反应结合,从简单廉价的原料出发,快速高效构建了基于氢键作用的磺酰胺类AIE分子3,并对其进行了结构表征和性质测试。Hydrogen bonding plays a significant role in both chemistry and life science.Aggregation-induced emission(AIE)is a cutting-edge area in organic chemistry and material research.Engaging students in related experimental practices can enhance their innovative capabilities.In this article,a practical experiment was designed.Merging the condensation reaction and the Hinsberg reaction from basic organic chemistry course,we efficiently synthesized a sulfonamide AIE molecule 3 with hydrogen bonding from simple and inexpensive starting materials.The synthesized compound was characterized and its properties were measured.

关 键 词：氢键 聚集诱导发光 磺酰胺 喹啉 荧光 

分 类 号：G64[文化科学—高等教育学] O6[文化科学—教育学]