碱性氧化铝催化有机反应的研究进展  

Research Progress on Organic Reactions Catalyzed by Basic Al_(2)O_(3)

作　　者：田凯迪 祝泽栋 王钰恒 蔡婷娜 刘阿利 郦勇 Tian Kaidi;Zhu Zedong;Wang Yuheng;Cai Tingna;Liu Ali;Li Yong(Shaoxing University,Shaoxing 312000,China)

机构地区：[1]绍兴文理学院,浙江绍兴312000

出　　处：《广东化工》2025年第1期79-82,共4页Guangdong Chemical Industry

基　　金：国家自然科学基金(21801167)。

摘　　要：碱性氧化铝表面兼具Lewis酸和Brønsted碱位点,可作为固体酸或固体碱促进包括缩合反应、氧化还原反应、取代反应在内的一系列有机转化。其作为催化剂,有成本低、可再生和环境友好等优势,契合绿色化学的要求。本文综述了近二十年来碱性氧化铝催化有机反应的研究进展,按照反应类型将其分类,并对碱性氧化铝与机械化学、纳米改性等新技术的结合使用前景进行了展望。Basic Al_(2)O_(3) surfaces possess both Lewis acid and Brønsted base sites,enabling them to function as solid acids or solid bases that facilitate a range of organic transformations,including condensation reactions,oxidation-reduction reactions,and substitution reactions.As a catalyst,basic Al_(2)O_(3) offers advantages such as cost-effectiveness,renewability,and environmental friendliness,aligning with the principles of green chemistry.This article provides an overview of the research progress in organic reactions catalyzed by alkaline alumina over the past two decades,categorizing them based on reaction types,and explores the potential of combining basic Al_(2)O_(3) with emerging technologies like mechanochemistry and nano-modification.

关 键 词：碱性氧化铝 绿色化学 缩合反应 氧化还原反应 取代反应 

分 类 号：TQ[化学工程]