聚苯醚型邻苯二甲腈树脂及其复合材料  

Polyphenylene ether type phthalonitrile resin and its composite materials

作　　者：张鑫伟 陆奇 王芳 刘敏 周权[1] ZHANG Xinwei;LU Qi;WANG Fang;LIU Min;ZHOU Quan(Key Laboratory of Specially Functional Polymeric Materials and Related Technology(Ministry of Education),School of Material Science and Engineering,East China University of Science and Technology,Shanghai 200237,China;Zhejiang Chennuo Polymer Materials Co.,Ltd.,Jiaxing 314204,China)

机构地区：[1]华东理工大学材料科学与工程学院,特种功能高分子材料及相关技术教育部重点实验室,上海200237 [2]浙江晨诺高分子材料有限公司,嘉兴314204

出　　处：《复合材料学报》2025年第1期191-199,共9页Acta Materiae Compositae Sinica

基　　金：国家自然科学基金(52173074);中央高校基本科研业务费专项资金(JKD01231701)。

摘　　要：为保留聚苯醚树脂优异介电性能的同时提升其耐溶剂性和热稳定性,拓宽其在高频高速覆铜板领域的应用,本文以K_(2)CO_(3)为缚酸剂,通过4-硝基邻苯二甲腈的亲核取代合成了一种聚苯醚型邻苯二甲腈树脂(PPOCN)。通过FTIR、DSC、TGA、流变性分析对树脂的结构、固化行为、耐热性以及加工性能进行了综合分析,通过介电分析仪、动态热机械分析及力学性能测试评估了复合材料的各项性能。结果表明:PPOCN具备交联反应活性,固化物的玻璃化转变温度(T_(g))为295℃,5wt%热失重温度(T_(d5%))为419.3℃,与聚苯醚原料相比热稳定性显著提高。以PPOCN为基体树脂、二氨基二苯甲烷(DDM)为固化剂制备的纤维增强复合材料具备优异的力学性能和介电性能,弯曲强度为863.9 MPa,层间剪切强度为68.6 MPa,1 GHz频率下的介电常数为3.15,损耗角正切为0.003。PPOCN在保留了聚苯醚树脂优异介电性能的同时,兼具优异的力学性能和优良的热性能。In order to preserve the excellent dielectric properties of polyphenylene oxide resin while improving its solvent resistance and thermal stability,and expand its application in the field of high-frequency and high-speed copper clad laminates,this paper synthesized a polyphenylene oxide type phthalonitrile resin(PPOCN)through nucleophilic substitution of 4-nitrophthalonitrile using K_(2)CO_(3) as a binding agent.A comprehensive analysis was conducted on the structure,curing behavior,heat resistance,and processing performance of the resin through FTIR,DSC,TGA,and rheological analysis.The various properties of the composite material were evaluated through dielectric analyzer,dynamic thermomechanical analysis,and mechanical performance testing.The results show that PPOCN has crosslinking reaction activity,and the glass transition temperature(T_(g))of the cured product is295℃,and the 5wt%thermal weight loss temperature(T_(d5%))is 419.3℃.Compared with the raw material of polyphenylene oxide,the thermal stability of PPOCN is significantly improved.The fiber reinforced composite material prepared with PPOCN as the matrix resin and diaminodiphenylmethane(DDM)as the curing agent has excellent mechanical and dielectric properties,with a bending strength of 863.9 MPa,interlayer shear strength of 68.6 MPa,dielectric constant of 3.15 at 1 GHz frequency,and loss tangent of 0.003.PPOCN retains the excellent dielectric properties of polyphenylene oxide resin while also possessing excellent mechanical and thermal properties.

关 键 词：热固性树脂 聚苯醚 邻苯二甲腈 覆铜板 介电性能 

分 类 号：TB332[一般工业技术—材料科学与工程]