响应面法优化桐油基多元醇制备环氧树脂的研究  

Study on the Preparation of Epoxy Resin by Tung Oil-based Polyol Optimized by Response Surface Method

作　　者：李奕彤 陈祉含 张中华 齐华春[1] 牛笑一[1] LI Yi-tong;CHEN Zhi-han;ZHANG Zhong-hua;QI Hua-chun;NIU Xiao-yi(Key Laboratory of Wood Materials Science and Engineering,Beihua University,Jilin 132013,Jilin,P.R.China)

机构地区：[1]北华大学木质材料科学与工程重点实验室,吉林省吉林市132013

出　　处：《林产工业》2025年第2期7-11,共5页China Forest Products Industry

基　　金：吉林省科技厅重大科技专项课题(YDZJ202203CGZH033);国家级大创项目120723013。

摘　　要：桐油酸甘油酯与多元醇在碱的催化下进行酯交换反应得到桐油基多元醇。在碱性环境下,对桐油基多元醇进行开环和闭环两步环氧化,合成得到环氧树脂。利用响应面Box-Behnken试验设计方法,研究不同NaOH添加量、反应时间、反应温度对桐油基环氧树脂性能的影响。结果表明:优化合成条件为:NaOH添加量为双酚A质量的0.42,反应温度为79℃,反应时间为7.3 h,此时桐油基环氧树脂的胶合强度为0.79 MPa。In this study,tung oil-based polyols were obtained by transesterification of tung oil glycerol ester and polyols under the catalysis of alkali.Epoxy resin was synthesized by ring-opening and closed-loop two-step epoxidation of tung oil-based polyols in alkaline environment.The effects of different NaOH additions,reaction time,and reaction temperature on the properties of tung oil-based epoxy resin were studied by response surface Box-Behnken experimental design method.The results showed that the optimum synthesis conditions were as follows:the addition amount of NaOH was 0.42 of the mass of bisphenol A,the reaction temperature was 79℃,and the reaction time was 7.3 h.At this time,the bonding strength of tung oil-based epoxy resin was 0.79 MPa.

关 键 词：响应面法 桐油 桐油基多元醇 双酚A 环氧树脂 

分 类 号：TS6[轻工技术与工程] TS396