Hydroformylation of Oleyl Alcohol Catalyzed by Rh-OPGPP Complex  

作　　者：Fan Zhi KONG Yan Hua WANG Zi Lin JIN 

机构地区：[1]State Key Laboratory of Fine Chemicals,Dalian University of Technology,Dalian 116012

出　　处：《Chinese Chemical Letters》2002年第6期497-498,共2页中国化学快报(英文版)

基　　金：The authors are grateful to the financial support from the National Natural Science Foundation of China(Grant No.29906001)

摘　　要：Polyether-tailored phosphite modified rhodium complex formed in situ was highly active in the hydroformylation of oleyl alcohol in nonaqueous phosphite/heptane system where the phosphite acted both as the ligand and the second phase. This catalyst was easily separated by simple decantation and can be used for five times with only a slight decrease in activity.Polyether-tailored phosphite modified rhodium complex formed in situ was highly active in the hydroformylation of oleyl alcohol in nonaqueous phosphite/heptane system where the phosphite acted both as the ligand and the second phase. This catalyst was easily separated by simple decantation and can be used for five times with only a slight decrease in activity.

关 键 词：PHOSPHITE HYDROFORMYLATION oleyl alcohol nonaqueous biphasic catalysis. 

分 类 号：O643.3[理学—物理化学]