HYDROFORMYLATION

作品数:62被引量:59H指数:4
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相关作者:丁云杰李存耀姜淼刘佳严丽更多>>
相关机构:中国科学院中国科学院大学更多>>
相关期刊:《Journal of Chemistry and Chemical Engineering》《Chinese Journal of Structural Chemistry》《Science Bulletin》《International Journal of Organic Chemistry》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划中国科学院战略性先导科技专项霍英东教育基金更多>>
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Tandem hydroformylation/hydrogenation of olefins to alcohols using atomically dispersed bifunctional catalysts
《Science China Chemistry》2024年第11期3706-3711,共6页Ying Zhang Liyang Liu Ziyue Wang Xingcong Zhang Xiaohui He Hongbing Ji 
supported by the National Key Research and Development Program Nanotechnology Specific Project (2020YFA0210900);the Guangdong Natural Science Funds for Distinguished Young Scholar (2022B1515020035);the National Natural Science Foundation of China (22078371, U22A20428, 21961160741);the Special Fund for Science and Technology Innovation Teams of Shanxi Province (202304051001007)。
Tandem hydroformylation/hydrogenation of olefins to alcohols is an appealing and challenging route that has received continuous interest. Herein, we report a bifunctional atomically dispersed Rh and Co catalyst(Rh Co/...
关键词:TANDEM hydroformylation/hydrogenation ALCOHOLS BIFUNCTIONAL single atom catalysts 
Activity promotion of Rh_(1)Ca_(x)/Al_(2)O_(3) single-atom catalyst in 1-octene hydroformylation:a volcano curve exists between Ca adding ratio and catalytic activity被引量:2
《Science China Chemistry》2024年第4期1187-1192,共6页Hao Zhang Xingcong Zhang Xilun Wang Qingdi Sun Hao Liu Hongbing Ji Xiaohui He 
supported by the National Key Research and Development Program Nanotechnology Specific Project(2020YFA0210900);the Science and Technology Key Project of Guangdong Province,China(2020B010188002);Guangdong Natural Science Funds for Distinguished Young Scholar(2022B1515020035);Guangdong Provincial Key R&D Program(2019B110206002);the National Natural Science Foundation of China(22078371,21938001,21961160741);the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program(2017BT01C102);the Natural Science Foundation of Guangdong Province(2020A1515011141);the Science and Technology Project of Guangzhou City,China(202102020461)。
Single-atom catalysts(SACs)are considered the best candidates for olefin hydroformylation due to their combined advantages of homogeneous and heterogeneous catalysts.Unlike conventional organo-phosphine modification,R...
关键词:HYDROFORMYLATION bimetallic single-atom catalysts RHODIUM heterogeneous catalyst 
Carbon Monoxide as C1 Building Block in Fine Chemical Synthesis被引量:1
《Chinese Journal of Chemistry》2024年第2期199-221,共23页Rui M.B.Carrilho Mario J.F.Calvete Gabor Mikle Laszlo Kollar Mariette M.Pereira 
Portuguese Agency for Scientific Research"Fundacao para a Ciencia e a Tecnologia"(FCT)and COMPETE2020-UE,for funding through projects UIDB/00070/2020,UIDP/00070/2020,UIDB/00313/2020,UIDP/00313/2020 and UIDB/00285/2020 to Coimbra Chemistry Centre(CQC);NKFIH for funding through project TKP2021-EGA-17.
Carbon monoxide(CO)has become one of the most relevant and versatile renewable C1 building blocks for chemical synthesis,especially in the fine chemicals industry,due to the development of efficient and selective cata...
关键词:Carbon monoxide Fine chemicals CARBONYLATION HYDROFORMYLATION C-H functionalization 
Efficient Heterogeneous Hydroformylation over Zeolite-Encaged Isolated Rhodium Ions
《CCS Chemistry》2023年第7期1526-1539,共14页Weixiang Shang Bin Qin Mingyang Gao Xuetao Qin Yuchao Chai Guangjun Wu Naijia Guan Ding Ma Landong Li 
This work was supported by the National Natural Science Fund of China(grant nos.21872072 and 22025203);the Frontiers Science Center for New Organic Matter,Nankai University(grant no.63181206);Haihe Laboratory of Sustainable Chemical Transformations,Tianjin.
Alkene hydroformylation is an extremely important industry process currently accomplished via homogeneous catalysis.Heterogeneous hydroformylation is being avidly pursued as a more economical and sustainable process.H...
关键词:ZEOLITE isolated rhodium site heterogeneous catalysis HYDROFORMYLATION mechanism 
Hydroformylation over polyoxometalates supported single-atom Rh catalysts
《National Science Open》2023年第2期161-174,共14页Shixiang Feng Qi Yu Xinbin Ma Xiaohu Yu Ning Yan 
supported by the National Natural Science Foundation of China(92061109 and 22273053);the Natural Science Basic Research Program of Shaanxi(2021JCW-20 and 2022KJXX-18).
Atomic dispersion of Rh on phosphotungstic acid(PTA)salts was achieved by a self-assembled precipitation method using alkali metal ions as coprecipitation reagents.During styrene hydroformylation,the supported Rh sing...
关键词:POLYOXOMETALATES Rh single-atom HYDROFORMYLATION SELF-ASSEMBLY STYRENE 
Examination of Milstein Ru-PNN and Rh-Tribi/Tetrabi dual metal catalyst for isomerization-linear-hydroformylation of C4 raffinate and internal olefins
《Green Synthesis and Catalysis》2022年第1期40-45,共6页Runtong Zhang Xin Yan Shao-Tao Bai Caiyou Chen Bozhao Nan Baode Ma Jialin Wen Xumu Zhang 
R.Zhang gratefully acknowledges the Free Exploration Fund from the Science and Technology Innovation Committee of Shenzhen(No.JCYJ20170817104824122);We are grateful for the financial support from the National Natural Science Foundation of China(No.22001113);the Guangdong Provincial Key Laboratory of Catalysis(No.2020B121201002).
Isomerization-linear-hydroformylation is demanding,however,not an addressed issue,for the production of value-added linear aldehydes by converting cheap and abundant internal alkenes available from bio-&petrochemical ...
关键词:Isomerization-linear-hydroformylation Ru-PNN Dual metal catalysis RAFFINATE Internal alkenes 
Synthesis of rac-α-aryl propionaldehydes via branched-selective hydroformylation of terminal arylalkenes using water-soluble Rh-PNP catalyst被引量:1
《Chinese Chemical Letters》2022年第2期830-834,共5页Peng Gao Miaolin Ke Tong Ru Guanfeng Liang Fen-Er Chen 
financial support from the National Natural Science Foundation of China (No.21902032)。
This work detailed the preparation of a class of water-soluble PNP ligands that differed by the nature of the substitute on phenyl ring of ligands. These ligands were incorporated into water-soluble rhodium-PNP comple...
关键词:Aryl propionaldehydes HYDROFORMYLATION Water-soluble PNP ligands Regioselectivity RHODIUM 
Monolithic membrane reactors based on supported ionic liquid phase(SILP)materials–hydroformylation and water-gas shift case studies
《Green Chemical Engineering》2021年第4期339-341,共3页Markus Schorner Patrick Wolf Marco Haumann 
support from the European Commission within the H2020 projects ROMEO(grant agreement number 680395);MACBETH(grant agreement number 869896).
Homogeneous catalysts,usually being active in liquid environment,offer several benefits for highly selective processes.However,the often tedious product separation and catalyst recycling,requiring energy and chemical ...
关键词:IONIC CATALYST LIQUID 
Enhancing the activity,selectivity,and recyclability of Rh/PPh_(3) system‐catalyzed hydroformylation reactions through the development of a PPh_(3)‐derived quasi‐porous organic cage as a ligand被引量:4
《Chinese Journal of Catalysis》2021年第7期1216-1226,共11页Wenlong Wang Cunyao Li Heng Zhang Jiangwei Zhang Lanlu Lu Zheng Jiang Lifeng Cui Hongguang Liu Li Yan Yunjie Ding 
中国科学院战略性先导科技专项(XDA21020300,XDB17020400);国家重点研发计划(2017YFB0602203);国家自然科学基金(21972018);东莞理工学院新能源材料研究中心(KCYCXPT2017005);东莞理工学院科研启动基金(KCYKYQD2017015).
In contrast to heterogeneous network frameworks(e.g.,covalent organic frameworks and metal‐organic frameworks)and porous organic polymers,porous organic cages(POCs)are soluble molecules in common organic solvents tha...
关键词:HYDROFORMYLATION TRIPHENYLPHOSPHINE Porous organic cages Chemical selectivity Linear‐regioselectivity 
Hydroformylation of formaldehyde to glycolaldehyde:An alternative synthetic route for ethylene glycol被引量:2
《Chinese Journal of Chemical Engineering》2021年第7期3-16,共14页Jie Wei Maoshuai Li Meiyan Wang Shixiang Feng Weikang Dai Qi Yang Yi Feng Wanxin Yang Cheng Yang Xinbin Ma 
supported by the National Key Research and Development Program of China(2018YFA0704501).
Hydroformylation of formaldehyde to glycolaldehyde(GA),as a vital reaction in both direct and indirect process of syngas to ethylene glycol(EG),shows great advantages in the aspects of the process complexity and clean...
关键词:FORMALDEHYDE SYNGAS HYDROFORMYLATION GLYCOLALDEHYDE Ethylene glycol Mechanism 
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