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supported by the National Key Research and Development Program Nanotechnology Specific Project (2020YFA0210900);the Guangdong Natural Science Funds for Distinguished Young Scholar (2022B1515020035);the National Natural Science Foundation of China (22078371, U22A20428, 21961160741);the Special Fund for Science and Technology Innovation Teams of Shanxi Province (202304051001007)。
Tandem hydroformylation/hydrogenation of olefins to alcohols is an appealing and challenging route that has received continuous interest. Herein, we report a bifunctional atomically dispersed Rh and Co catalyst(Rh Co/...
supported by the National Key Research and Development Program Nanotechnology Specific Project(2020YFA0210900);the Science and Technology Key Project of Guangdong Province,China(2020B010188002);Guangdong Natural Science Funds for Distinguished Young Scholar(2022B1515020035);Guangdong Provincial Key R&D Program(2019B110206002);the National Natural Science Foundation of China(22078371,21938001,21961160741);the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program(2017BT01C102);the Natural Science Foundation of Guangdong Province(2020A1515011141);the Science and Technology Project of Guangzhou City,China(202102020461)。
Single-atom catalysts(SACs)are considered the best candidates for olefin hydroformylation due to their combined advantages of homogeneous and heterogeneous catalysts.Unlike conventional organo-phosphine modification,R...
Portuguese Agency for Scientific Research"Fundacao para a Ciencia e a Tecnologia"(FCT)and COMPETE2020-UE,for funding through projects UIDB/00070/2020,UIDP/00070/2020,UIDB/00313/2020,UIDP/00313/2020 and UIDB/00285/2020 to Coimbra Chemistry Centre(CQC);NKFIH for funding through project TKP2021-EGA-17.
Carbon monoxide(CO)has become one of the most relevant and versatile renewable C1 building blocks for chemical synthesis,especially in the fine chemicals industry,due to the development of efficient and selective cata...
This work was supported by the National Natural Science Fund of China(grant nos.21872072 and 22025203);the Frontiers Science Center for New Organic Matter,Nankai University(grant no.63181206);Haihe Laboratory of Sustainable Chemical Transformations,Tianjin.
Alkene hydroformylation is an extremely important industry process currently accomplished via homogeneous catalysis.Heterogeneous hydroformylation is being avidly pursued as a more economical and sustainable process.H...
supported by the National Natural Science Foundation of China(92061109 and 22273053);the Natural Science Basic Research Program of Shaanxi(2021JCW-20 and 2022KJXX-18).
Atomic dispersion of Rh on phosphotungstic acid(PTA)salts was achieved by a self-assembled precipitation method using alkali metal ions as coprecipitation reagents.During styrene hydroformylation,the supported Rh sing...
R.Zhang gratefully acknowledges the Free Exploration Fund from the Science and Technology Innovation Committee of Shenzhen(No.JCYJ20170817104824122);We are grateful for the financial support from the National Natural Science Foundation of China(No.22001113);the Guangdong Provincial Key Laboratory of Catalysis(No.2020B121201002).
Isomerization-linear-hydroformylation is demanding,however,not an addressed issue,for the production of value-added linear aldehydes by converting cheap and abundant internal alkenes available from bio-&petrochemical ...
financial support from the National Natural Science Foundation of China (No.21902032)。
This work detailed the preparation of a class of water-soluble PNP ligands that differed by the nature of the substitute on phenyl ring of ligands. These ligands were incorporated into water-soluble rhodium-PNP comple...
support from the European Commission within the H2020 projects ROMEO(grant agreement number 680395);MACBETH(grant agreement number 869896).
Homogeneous catalysts,usually being active in liquid environment,offer several benefits for highly selective processes.However,the often tedious product separation and catalyst recycling,requiring energy and chemical ...
In contrast to heterogeneous network frameworks(e.g.,covalent organic frameworks and metal‐organic frameworks)and porous organic polymers,porous organic cages(POCs)are soluble molecules in common organic solvents tha...
supported by the National Key Research and Development Program of China(2018YFA0704501).
Hydroformylation of formaldehyde to glycolaldehyde(GA),as a vital reaction in both direct and indirect process of syngas to ethylene glycol(EG),shows great advantages in the aspects of the process complexity and clean...