从α－蒎烯合成紫苏糖的研究  

STUDIES ON SYNTHESIS OF FERILLARTINE FROM α-PINENE

作　　者：郑延华[1] 卢礼灿[1] 

机构地区：[1]湘潭大学化学系

出　　处：《湘潭大学自然科学学报》1995年第1期58-61,共4页Natural Science Journal of Xiangtan University

摘　　要：紫苏糖又名紫苏亭，是一种高甜、低热的优质甜味剂，可作为饮料、糕点、烟草、牙膏和药物等的甜味剂和防腐剂，以及作为保健食品的添加剂．本文介绍了从α－蒎烯出发经二氧化硒选择性氧化、铜－锌催化异构化和肟化，合成紫苏糖的详细情况，探讨了各种因素对反应的影响．Using α-pinene as raw materials, the perillarine can be preparedb by selective oxidation with selenium dioxide, isomerization with copper-zinc catalyst under reduced pressure and oximation. It is a fine sweetener to possess high sweentness and low caloricity.In this paper, affections of the reaction conditions on yield were studied and optimum condition were given. In the synthesis of myrtenal, we used vanadium pentoxide as calatyst. In the catalytic ismerization of myrtnal, we used nitrogen as protectyve gas, The sum yield is raised fron 26% to 45%.

关 键 词：紫苏糖 Α-蒎烯 紫苏醛 桃金烯醛 选择性氧化 异构化 肟化 甜味剂 松节油 

分 类 号：TS264.9[轻工技术与工程—发酵工程]