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作 者:顾广瑞[1] 李英爱[1] 陶艳春[2] 何志[1] 殷红[1] 李卫青[1] 赵永年[1]
机构地区:[1]吉林大学超硬材料国家重点实验室 [2]吉林大学超分子结构和谱学开放实验室,吉林长春130023
出 处:《液晶与显示》2003年第1期10-13,共4页Chinese Journal of Liquid Crystals and Displays
基 金:国家自然科学基金资助项目(59831040)
摘 要:利用射频磁控溅射方法,在n型(100)Si基底上沉积了不同厚度(54~135nm)的纳米氮化硼(BN)薄膜。红外光谱分析表明,BN薄膜结构为六角BN(h BN)相(1380cm-1和780cm-1)。在超高真空系统中测量了不同膜厚BN薄膜的场发射特性,发现BN薄膜的场发射特性与膜厚关系很大,阈值电场随着厚度的增加而增大。由于BN薄膜和Si基底界面间存在功函数差,使得Si基底中电子转移到BN薄膜的导带,在外电场作用下隧穿BN表面势垒,发射到真空。Nanometer Boron Nitride(BN) thin films with various thickness(54~135nm) were prepared on the (100)oriented surface of nSi(0.008~0.02Ω·m) by r.f. magnetic sputtering physical vapor deposition(PVD). There were only two absorption peaks of hBN at about 1 380 cm-1 and 780 cm-1 by Fourier transform infrared spectra for the BN thin films. The field emission characteristics of thin BN films were measured in a super high vacuum system. It is found that the field emission characteristics of thin BN films depends evidently on the thickness of the films. The threshold voltage increases with the increase of the thickness in nanometer thickness range. This is attributed to the work function difference between BN thin film and Si substrate. Electrons are transferred from substrate Si to conduction band of BN thin film, and are emitted from BN to vacuum tunneling through the potential barrier at the surface of the BN thin film under exterior electric field action.
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