Synthesis of Novel Carbosilane Dendrimers with Myo-inositol Cores  

作　　者：Zhi Jun YU1 Qi Zhen ZHANG Qi Feng ZHOU 

机构地区：[1]School of Chemistry and Chemical Engineering, Shandong University, Ji'nan 250100 [2]College of Chemistry and Molecular Engineering, Peking University, Beijing100871

出　　处：《Chinese Chemical Letters》2003年第5期465-467,共3页中国化学快报（英文版）

基　　金：We are grateful to the National Natural Science Foundation of China for financial support(No.29874020).

摘　　要：The preparation of carbosilane dendrimers with cores of myo-inositol and the outmost periphery groups of allyl groups has been reported. By using alternate hydrosilylation and alkenylation reactions, the dendrimer have been carried up to the third generation with 48 allyl groups on the periphery.The preparation of carbosilane dendrimers with cores of myo-inositol and the outmost periphery groups of allyl groups has been reported. By using alternate hydrosilylation and alkenylation reactions, the dendrimer have been carried up to the third generation with 48 allyl groups on the periphery.

关 键 词：Carbosilane dendrimer MYO-INOSITOL divergent method HYDROSILYLATION Grignard reagent. 

分 类 号：O627.41[理学—有机化学] O632.12[理学—化学]