联吡啶与铼、钌络合物的核磁共振谱分析  

Analysis of Bipyridyl Organometallic Rhenium(Ⅰ) and Ruthenium(Ⅱ) Complexes by NMR

作　　者：孙世国[1] 徐勇前[1] 彭孝军[1] 孙立成[1] 

机构地区：[1]大连理工大学精细化工国家重点实验室,辽宁大连116012

出　　处：《分析测试学报》2003年第3期5-7,共3页Journal of Instrumental Analysis

基　　金：国家自然科学基金资助项目(20128005)

摘　　要：对2,2′_联吡啶_4,4′_二羧酸乙酯与过渡金属铼络合物 (化合物1)和钌络合物 (化合物2)的结构进行了核磁共振与电喷雾质谱 (ESI_MS)的分析研究 ;利用 1H - 1HCOSY、HSQC、HMBC等二维相关NMR谱准确表征了化合物的结构。Organometallic complex of diethyl _2,2′ _ bipyridine _ 4,4′ _ dicarboxylate with rhenium(Ⅰ)(compound 1) and ruthenium(Ⅱ)(compound 2) were studied by NMR and electrospray ionization MS. Their structures were elucidated by use of 2D _ NMR spectroscopy such as 1H-1H COSY, HSQC and HMBC. The long _ range couplings were detected clearly.

关 键 词：联吡啶 铼 钌 络合物 核磁共振谱 电喷雾质谱 太阳能电池 光敏染料 

分 类 号：TM914.4[电气工程—电力电子与电力传动] TQ615[化学工程—精细化工]