香兰素对甲苯胺希夫碱硝酸稀土配合物的合成  

Complexes of Rare Earth Nitrate with Schiff Base Derived from Vanillin and p-Toluidine

作　　者：刘国发[1] 刘晓勋[1] 曹锡章 

机构地区：[1]吉林大学化学系

出　　处：《吉林大学自然科学学报》1992年第3期105-108,共4页Acta Scientiarum Naturalium Universitatis Jilinensis

基　　金：国家自然科学基金

摘　　要：制备了香兰素(3-甲氧基-4-羟基苯甲醛)对甲苯胺希夫(Schiff)碱硝酸稀土配合物。该配合物由一个中心稀土离子,二个单齿配位希夫碱,二个双齿配位硝酸根和一个外界硝酸根组成,中心稀土离子的配位数是6,其一般式为[LnL_2(NO_3)_2]NO_3(Ln=La, Ce, Pr, Nd, Sm, Eu; L=希夫碱配体)。Complexes of rare earth nitrate Schiff base derived from vanillin (3-methoxy-4-hy-droxybenzaldehyde) and p-toluidine were synthesized and characterized.Two Schiff base ligands and two nitrate radicals are bound to the rare earth; one nitrate radicals is in the outer coordination sphere. The metal ion of the complexes exhibits a coordination number of six. Their composition is LnC_(30)H_(30)N_5O_(13) and formula [LnL_2 (NO_3)_2]NO_3 (Ln=La, Ce, Pr, Nd, Sm, Eu, L=Schiff base ligand).

关 键 词：香兰素 稀土 配合物 西佛碱 

分 类 号：O614.33[理学—无机化学]