Remarkably Accelerated Regioselective Hydrogenolysis of Terminal Epoxides in the Presence of CoCl_2 or NiSO_4  

作　　者：沈鑫 唐朝军 伍贻康 

机构地区：[1]State Key Laboratory of Bioorganic & Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China

出　　处：《Chinese Journal of Chemistry》2003年第7期972-974,共3页中国化学（英文版）

基　　金：Project supported by the National Natural Science Foundation of China(Nos.20025207,20272071),Chinese Academy of Sciences and the Major State Basic Research Development Program(No.G2000077502).

摘　　要：The rate of atmospheric pressure hydrogenolysis of terminal e-poxides over palladium-charcoal to the corresponding methyl alcohols could be remarkably accelerated by introduction of Co-Cl2 or NiSO4.The rate of atmospheric pressure hydrogenolysis of terminal e-poxides over palladium-charcoal to the corresponding methyl alcohols could be remarkably accelerated by introduction of Co-Cl2 or NiSO4.

关 键 词：EPOXIDES HYDROGENOLYSIS COBALT nickel ring-open-ing 

分 类 号：O621[理学—有机化学]