失水山梨醇单月桂酸酯的一步法合成  

One-step synthesis of sorbitan mono-laurate

作　　者：曾贵玉[1] 倪永全[2] 

机构地区：[1]中国工程物理研究院化工材料研究所,四川绵阳621900 [2]无锡轻工大学,江苏无锡214036

出　　处：《化学研究与应用》2003年第4期581-582,共2页Chemical Research and Application

摘　　要：sorbitan monolaurate(Span 20)is a famous nonionic surfactant which possesses many excellent properties such as emulsifying,dispersing,nontoxic,nonirritant and lowvolatilization.Span 20 was synthesized from sorbitol and laurate by onestep method which made the etherification and esterification work simultaneously.The synthesis method was compared and the main influencing factors on the products color and three targets(acid number,hydroxide value and saponification value)such as reacting temperature and time were also studied.Finally,the suitable conditions for the synthesis of Span 20 products were obtained,i.e.,reaction temperature 215°C,reaction time 240 min and w(phosphoric acid)=043%.The analysis results showed that the experimenting samples’three targets were eligible,the color was ivory,and it’s monoester massfractions was higher than 90%.sorbitan monolaurate(Span 20)is a famous nonionic surfactant which possesses many excellent properties such as emulsifying,dispersing,nontoxic,nonirritant and lowvolatilization.Span 20 was synthesized from sorbitol and laurate by onestep method which made the etherification and esterification work simultaneously.The synthesis method was compared and the main influencing factors on the products color and three targets(acid number,hydroxide value and saponification value)such as reacting temperature and time were also studied.Finally,the suitable conditions for the synthesis of Span 20 products were obtained,i.e.,reaction temperature 215°C,reaction time 240 min and w(phosphoric acid)=043%.The analysis results showed that the experimenting samples'three targets were eligible,the color was ivory,and it's monoester massfractions was higher than 90%.

关 键 词：失水山梨醇单月桂酸酯 一步法 合成方法 山梨醇 月桂酸 皂化值 酸值 羟值 

分 类 号：TQ225.241[化学工程—有机化工]