2D NMR研究D-葡萄糖衍生的手性配体的绝对构型(英文)  

STUDY ON THE SYNTHESIS AND ABSOLUTE CONFIGURATIONS OF NOVEL CHIRAL LIGANDS DERIVED FROM D-GLUCOSE BY 2D NMR

作　　者：黄汉民[1] 黄为[1] 韩秀文[1] 陈惠麟[1] 郑卓[1] 

机构地区：[1]中国科学院大连化学物理研究所,辽宁大连116023

出　　处：《波谱学杂志》2003年第3期271-275,共5页Chinese Journal of Magnetic Resonance

基　　金：SupportedbyNationalNaturalScienceFoundationofChina ( 2 993 3 0 5 0 )

摘　　要：应用二维NOSEY技术 ,对以D 葡萄糖为手性源合成的 3种新型手性配体的结构和绝对构型进行了研究 ,并对此类化合物进行了计算机分子模拟 ,取得与NOSEY一致的结果 .The two dimensional Nuclear Overhauser Effect Spectroscopy (NOESY) technique was successfully applied to investigate the structures and absolute configurations of novel chiral ligands which were derived from D glucose. The results have also been confirmed by computational optimizing model data.

关 键 词：核磁共振 NOSEY 计算机分子模拟 手性配体 绝对构型 D-葡萄糖 结构分析 2DNMR 

分 类 号：O629.12[理学—有机化学] O641.4[理学—化学]