硝基化合物的不对称迈克尔加成反应  

Asymmetric Michael Additions of Nitro Compounds

作　　者：段新方[1] 

机构地区：[1]北京师范大学化学系,北京100875

出　　处：《有机化学》2003年第8期776-783,共8页Chinese Journal of Organic Chemistry

摘　　要：从以下三方面对硝基化合物的不对称迈克尔加成反应进行了较为详细的综述 :( 1)手性催化剂催化的迈克尔加成 ,( 2 )共轭硝基物与手性亲核试剂的迈克尔加成 ,( 3 )脂肪族硝基物对手性迈克尔加成受体的迈克尔加成 .Asymmetric Michael additions of nitro compounds are of remarkable importance in organic asymmetric synthesis due to their easy versatility of transformations. This paper reviews the recent advances of these reactions, which witnesses their extensive utilization in the syntheses of many important optically active compounds.

关 键 词：硝基化合物 不对称合成 迈克尔加成反应 手性催化剂 手性亲核试剂 脂肪族硝基物 共轭硝基物 

分 类 号：O621.25[理学—有机化学]