煤及其溶剂萃取产物的氮气吸附行为  

ADSORPTION BEHAVIORS FOR NITROGEN BY COAL, ITS EXTRACT FRACTIONS AND RESIDUES

作　　者：王飞[1] 张代钧[1] 李小鹏[1] 杨明莉[1] 

机构地区：[1]重庆大学资源及环境科学学院,四川重庆400044

出　　处：《燃料化学学报》2003年第5期395-399,共5页Journal of Fuel Chemistry and Technology

基　　金：西南资源开发与环境灾害控制工程教育部重点实验项目(教技司2000 170) ~~

摘　　要：用二硫化碳-N 甲基 2 吡咯烷酮(CS2 NMP)(1∶1,V V)混合溶剂,以及丙酮和吡啶将云南褐煤和南桐烟煤逐级萃取,去除萃取溶剂后得到各级固态级分。通过ASAP2010型比表面积及孔快速测试仪,对原煤及萃取级分的氮气吸附行为进行测试,分别用BET模型、线型方程对实验结果进行拟合。结果表明对于萃取率较高的煤,溶剂萃取能较大地增加其孔隙率;煤对氮气的吸附行为遵从Henry定律,因此只需在氮气饱和气压的沸点(77K)下,测出少数几个压力点的吸附量,就可以得到一条准确的等温吸附线。Yunnan lignite and Nantong bituminous coal were extracted with a carbon disulfideNmethyl2pyrrolidinone (CS2-NMP) mixed solvent, actone and pyridine at room temperature in turn,and the solid powders were gained after removal of the solvent Adsorption behaviors of nitrogen by the coal, its extract fractions and residuals were investigated using Accelerated Surface Area and Porosimetry (ASAP) 2010 apparatus, and the experimental data were fitted by BET equation and y=kx+b Results showed that solvent extraction can increase the porosity for the coal with high extraction yield, and the nitrogen adsorption behaviors of coal complied with the Henry law This demonstrated that, at the saturated temperature of nitrogen (77?K),an exact nitrogen adsorption isotherm can be obtained from few data values of adsorption volumes

关 键 词：煤 萃取级分 残余物 等温吸附线 

分 类 号：TQ531.5[化学工程—煤化学工程]