不对称催化氢甲酰化中高效手性配体的进展  

Progress in Chiral Ligands for Asymmetric Catalytic Hydroformylation

作　　者：任运来[1] 赵文成[1] 吕士杰[1] 

机构地区：[1]中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室,兰州730000

出　　处：《化学进展》2004年第2期266-272,共7页Progress in Chemistry

基　　金：国家自然科学基金重点资助项目 (No .2 99330 5 0 )

摘　　要：比较系统地总结了应用于不对称催化氢甲酰化方面各类配体的合成、设计思路及性能 ,侧重于评述高效配体的最新进展。Crucial to the success in asymmetric hydroformylation is the design and synthesis of ligands. In the last decades, a number of excellent ligands have been found. But most of them are diphosphine or diphosphite ligands. Thus the features, development and applications of chiral ligands on asymmetric catalytic hydroformylation are the major focus of this review. Additionally, their mechanistic and conceptual background is included with 72 references.

关 键 词：不对称催化 氢甲酰化 手性配体 合成 设计 烯烃 羰基 醛 

分 类 号：O623.51[理学—有机化学] O621.3[理学—化学]