有机化合物极谱催化波研究的进展  

Progress in the Study on the Polarographic Catalytic Wave of Organic Compound

作　　者：过玮[1] 何平[2] 宋俊峰[2] 

机构地区：[1]西北大学化学系,西安710069 [2]西北大学分析科学研究所,西安710069

出　　处：《化学学报》2004年第10期929-934,共6页Acta Chimica Sinica

基　　金：国家自然科学基金 (No.2 98750 1 7)资助项目

摘　　要：评述有机化合物极谱催化波研究的进展 .建议有机化合物极谱催化波的主要类型及其命名分别为 :( 1)平行催化波 ,包括平行催化波、诱导吸附 -平行催化波和缔合 -平行催化波 ;( 2 )平行催化氢波 ,包括平行催化氢波和缔合 -平行催化氢波 .简要介绍蛋白质、黄酮类化合物、甾族类化合物、醌类化合物、α ,β 不饱和羰基化合物。The advances in polarographic catalytic wave of organic compound in the presence of oxidant are reviewed with 62 references. The classification and name of the catalytic wave are proposed as follows: (1) the parallel catalytic wave, which includes the parallel catalytic wave, the induced adsorption-parallel catalytic wave and the association-parallel catalytic wave. (2) the parallel catalytic hydrogen wave, which includes the parallel catalytic hydrogen wave and the association-parallel catalytic hydrogen wave. The polarographic catalytic waves of organic compounds, such as protein, flavone, steroide, quinone, alpha, beta-unsaturated carbonyl compound, nitrogen-containing substances and charged surfactants, and their application are briefly introduced.

关 键 词：有机化合物 极谱催化波 平行催化波 自由基 氧化剂 电分析化学 

分 类 号：O657.14[理学—分析化学]