褐煤树脂醇类化学组成与分布特征  

Chemical Constituents and Distributive Characteristics of “the Alcohols”in Brown Coal Resins Separated from Montan Waxes from Liaohu and Xundian Brown Coals

作　　者：李宝才[1] 张健[1] 周梅村[1] 张惠芬[1] 

机构地区：[1]昆明理工大学生物与化学工程学院,云南昆明650224

出　　处：《昆明理工大学学报（理工版）》2004年第3期82-86,90,共6页Journal of Kunming University of Science and Technology(Natural Science Edition)

基　　金：煤炭科学基金和云南省应用基础基金资助项目 (项目编号 :97加 2 1714 )

摘　　要：对云南潦浒及寻甸褐煤树脂中醇类化学成分进行了GC -MS研究 ,探索褐煤树脂醇类作为药用资源的可能性 .实验结果表明 ,树脂醇由正构烷醇、正构酮 (甲基酮 )、甾醇类、五环三萜醇及五环三萜酮所组成 .褐煤树脂醇中均存在 2 4 -甲基 - 5 β(H) -胆甾烷 - 3β -醇 (C2 8H50 O ,MW .40 2 ) ,2 4 -乙基胆甾 - 5 ,2 2 -二烯 - 3β -醇 (C2 9H48O ,MW .41 2 ) ,2 4 -乙基 - 5α(H) -胆甾烷 -3β -醇 (C2 9H52 O ,MW .41 6) ,2 3,2 4 -二甲基胆甾 - 5 -烯 - 3β -醇 (C2 9H50 O ,MW .41 4) ,C2 9- 5 β(H) ,3β(OH) -甾醇 (C2 9H52 O ,MW .41 6) ,2 4 -异丙基胆甾 - 5 ,2 4 ( 2 8)E -二烯 - 3β -醇 (C30 H50O ,MW .42 6)等甾类物质 .To explore the possibilities of brown coal resins as Chinese medicine, is made on “the alcohols” in brown coal resins isolated from brown coal waxes extracted from Liaohu and Xundian(Yunnan province) brown coals the study. The experimental results show that “the alcohols” in brown coal resins mainly consist of normal long chain alcohols with carbon number from C 15 to C 30 (C 22 ,C 24 ,C 26 as major compositions for the series), long chain ketones with carbon number C 18 , C 23 , C 25 , C 27 , C 29 and 15- hentriacotanone, sterols, pentacyclic triterpene alcohols and pentacyclic triterpene ketones. In Xundian and Liaohu alcohol fraction, there exist 24-methyl-5β(H)-cholestane-3β-ol(C 28 H 50 O, MW.402), 24-ethyl-cholest-5,22 -dien-3β-ol(C 29 H 48 O, MW.412), 24-ethyl-5α(H)-cholestane-3β-ol(C 29 H 52 O, MW.416), 23,24-dimethyl -cholest -5-en- 3β-ol(C 29 H 50 O, MW.414), C 29 -5β(H),3β(OH)-sterol(C 29 H 52 O, MW.416), 24-isopropyl- cholest-5, and 24(28)E-dien- 3β-ol(C 30 H 50 O, MW.426), etc. Xundian and Liaohu brown coal resins will be served as resources of the Chinese medicine based on their chemical constituents.

关 键 词：褐煤树脂 树脂醇 生物活性物质 化学组成 药用资源 

分 类 号：TQ351.473[化学工程]