Modeling Preparative Chromatographic Separation of Heavy Rare Earth Elements and Optimization of Thulium Purification  

作　　者：Mark Max-Hansen Hans-Kristian Knutson Christian Jonsson Marcus Degerman Bernt Nilsson 

机构地区：[1]Department of Chemical Engineering,Lund University,Lund,Sweden

出　　处：《Advances in Materials Physics and Chemistry》2015年第5期151-160,共10页材料物理与化学进展（英文）

摘　　要：Rare Earth Elements are in growing demand globally. This paper presents a case study of applied mathematical modeling and multi objective optimization to optimize the separation of heavy Rare Earth Elements, Terbium-Lutetium, by means of preparative solid phase extraction chromatography, which means that an extraction ligand, HDEHP, is immobilized on a C18 silica phase, and nitric acid is used as an eluent. An ICP-MS was used for online detection of the Rare Earths. A methodology for calibration and optimization is presented, and applied to an industrially relevant mixture. Results show that Thulium is produced at 99% purity, with a productivity of 0.2 - 0.5 kg Tm per m3 stationary phase and second, with Yields from 74% to 99%.Rare Earth Elements are in growing demand globally. This paper presents a case study of applied mathematical modeling and multi objective optimization to optimize the separation of heavy Rare Earth Elements, Terbium-Lutetium, by means of preparative solid phase extraction chromatography, which means that an extraction ligand, HDEHP, is immobilized on a C18 silica phase, and nitric acid is used as an eluent. An ICP-MS was used for online detection of the Rare Earths. A methodology for calibration and optimization is presented, and applied to an industrially relevant mixture. Results show that Thulium is produced at 99% purity, with a productivity of 0.2 - 0.5 kg Tm per m3 stationary phase and second, with Yields from 74% to 99%.

关 键 词：Rare Earth Elements CHROMATOGRAPHY Model Calibration Optimization Multi-Objective HDEHP 

分 类 号：O6[理学—化学]