Waste Management in Propylene Epoxidation Process with the Use of Supercritical Fluid Media  

作　　者：F. M. Gumerov R. A. Kayumov R. A. Usmanov A. A. Sagdeev I. Sh. Abdullin R. F. Sharafeev 

机构地区：[1]Nizhnekamsk Institute of Chemical Technology (Branch),State Educational Institution, Kazan National Research Technological University, Kazan,Russia

出　　处：《American Journal of Analytical Chemistry》2012年第12期950-957,共8页美国分析化学（英文）

摘　　要：Experimental results on solubility of the styrene, phenol, methylphenylcarbinol, acetophenone, ethyl benzene, propylene glycol and molybdenum as a complex with Trilon B in supercritical CO2 obtained using a dynamic (flow) method are presented. The obtained data are described in the framework of Peng-Robinson equation. The results of the experients on the extraction of organic components from waste formed in the olefin epoxidation process at Nizhnekam-skneftekhim Inc., on the analysis of extract composition, and on the testing of the extract as an epoxidation catalyst are presented. The supercritical water oxidation (SCWO) process of epoxidation process waste was conducted in periodical and continuous mode. The analysis results of reaction product are given. Pilot experiments on dry sediment formation were conducted using Radio Frequency (RF) Inductively Coupled Plasma (ICP) of low pressure.Experimental results on solubility of the styrene, phenol, methylphenylcarbinol, acetophenone, ethyl benzene, propylene glycol and molybdenum as a complex with Trilon B in supercritical CO2 obtained using a dynamic (flow) method are presented. The obtained data are described in the framework of Peng-Robinson equation. The results of the experients on the extraction of organic components from waste formed in the olefin epoxidation process at Nizhnekam-skneftekhim Inc., on the analysis of extract composition, and on the testing of the extract as an epoxidation catalyst are presented. The supercritical water oxidation (SCWO) process of epoxidation process waste was conducted in periodical and continuous mode. The analysis results of reaction product are given. Pilot experiments on dry sediment formation were conducted using Radio Frequency (RF) Inductively Coupled Plasma (ICP) of low pressure.

关 键 词：Styrene Phenol Methylphenylcarbinol ACETOPHENONE Ethyl Benzene PROPYLENE GLYCOL Molybdenum SUPERCRITICAL Carbon Dioxide SOLUBILITY Dynamic Method Description of SOLUBILITY Peng—Robinson Equation SUPERCRITICAL Water Oxidation High-Frequency Induction Plasma 

分 类 号：O6[理学—化学]