The Synthesis of Arylsulfonylphthalimides and Their Reactions with Several Amines in Acetonitrile  

作　　者：Seyhan Ozturk Halil Kutuk 

机构地区：[1]不详

出　　处：《International Journal of Organic Chemistry》2011年第4期202-206,共5页有机化学国际期刊（英文）

摘　　要：In this study, several N-(p-substituted-arylsulfonyl)phthalimides (1a-e) were synthesized. The synthesized compounds were then examined with respect to their substitution reactions with t-butylamine, diethylamine, cyclohexylamine, and trans-1,2-diaminocyclohexane in acetonitrile. In order to determine the mechanism, substituent effect, activation entropy, and nucleophile effect were used as criteria.In this study, several N-(p-substituted-arylsulfonyl)phthalimides (1a-e) were synthesized. The synthesized compounds were then examined with respect to their substitution reactions with t-butylamine, diethylamine, cyclohexylamine, and trans-1,2-diaminocyclohexane in acetonitrile. In order to determine the mechanism, substituent effect, activation entropy, and nucleophile effect were used as criteria.

关 键 词：Arylsulfonyl PHTHALIMIDES Mechanism SUBSTITUENT Effect Activation Entropy 

分 类 号：O6[理学—化学]