Synthesis and Structure of a Host-Guest Inclusion System between C-propyl-o-toluidine-methyl-resorcin[4]arene and Ethanol Solvate  

作　　者：Lusi Chen Rurou Jiang Huatian Shi Aiquan Jia Qianfeng Zhang Lusi Chen;Rurou Jiang;Huatian Shi;Aiquan Jia;Qianfeng Zhang(Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, China)

机构地区：[1]Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, China

出　　处：《Journal of Materials Science and Chemical Engineering》2023年第12期22-33,共12页材料科学与化学工程（英文）

摘　　要：Tetra-bromo-methyl-resorcin[4]arene cavitands were synthesized and C-2 position amine functionalized to obtain C-propyl-o-toluidine-methyl-resorcin[4]arene cavitand 4, and the crystal containing one solvate molecule of ethanol was obtained in a dichloromethane-ethanol solvent system, its structure crystallized in the monoclinic space group P2₁/n, with a = 12.521(3) Å, b = 21.738(6) Å, c = 25.353(6) Å, α = 90˚, β = 102.372(4)˚, γ = 90˚, and Z = 4. The compound was determined by single-crystal X-ray diffraction and characterized by ¹H NMR, FT-IR and elemental analyses.Tetra-bromo-methyl-resorcin[4]arene cavitands were synthesized and C-2 position amine functionalized to obtain C-propyl-o-toluidine-methyl-resorcin[4]arene cavitand 4, and the crystal containing one solvate molecule of ethanol was obtained in a dichloromethane-ethanol solvent system, its structure crystallized in the monoclinic space group P2₁/n, with a = 12.521(3) Å, b = 21.738(6) Å, c = 25.353(6) Å, α = 90˚, β = 102.372(4)˚, γ = 90˚, and Z = 4. The compound was determined by single-crystal X-ray diffraction and characterized by ¹H NMR, FT-IR and elemental analyses.

关 键 词：arene CAVITAND Amine Functionalized Dichloromethane-Ethanol 

分 类 号：O62[理学—有机化学]