CAVITAND

作品数：9被引量：5H指数：2
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相关领域：理学更多>>
相关作者：汪翔林雨霖徐海任扬蔡健峰更多>>
相关机构：中南大学南京工业大学更多>>
相关期刊：《高等学校化学学报》《Chinese Journal of Structural Chemistry》《Journal of Materials Science and Chemical Engineering》《Chinese Journal of Chemistry》更多>>
相关基金：国家自然科学基金教育部科学技术研究重点项目更多>>
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Supramolecular prodrug vesicles for selective antimicrobial therapy employing a chemo-photodynamic strategy
《Chinese Chemical Letters》2025年第3期267-271,共5页Hao Sun Shengke Li Qian Liu Minzan Zuo Xueqi Tian Kaiya Wang Xiao-Yu Hu 
supported by the National Natural Science Foundation of China(No.22271154);Natural Science Foundation of Jiangsu Province(No.BK20211179);Innovation Support Program of Jiangsu Province(No.BZ2023055);Fundamental Research Funds for the Central Universities(No.NS2023033);China Postdoctoral Science Foundation(No.2023M731658);Achievement Transformation Project of Qinghai Province(No.2021-SF-145).
Supramolecular prodrug vesicles(H-4⊃B-2@MB)with selective antibacterial activity have been successfully constructed.Specifically,a natural antibiotic prodrug(B-2)with glutathione(GSH)-responsiveness was synthesized.Th...
关键词：Supramolecular prodrug Selective antibacterial activity Host-guest complex CAVITAND Combination therapy 
Synthesis and Structure of a Host-Guest Inclusion System between C-propyl-o-toluidine-methyl-resorcin[4]arene and Ethanol Solvate
《Journal of Materials Science and Chemical Engineering》2023年第12期22-33,共12页Lusi Chen Rurou Jiang Huatian Shi Aiquan Jia Qianfeng Zhang 
Tetra-bromo-methyl-resorcin[4]arene cavitands were synthesized and C-2 position amine functionalized to obtain C-propyl-o-toluidine-methyl-resorcin[4]arene cavitand 4, and the crystal containing one solvate molecule o...
关键词：arene CAVITAND Amine Functionalized Dichloromethane-Ethanol 
State-of-the-art and recent progress in resorcinarene-based cavitand
《Chinese Chemical Letters》2023年第10期27-34,共8页Kaiya Wang Qian Liu Li Zhou Hao Sun Xiaoquan Yao Xiao-Yu Hu 
supported by the Natural Science Foundation of Jiangsu Province(Nos.BK20200432,BK20211179);National Natural Science Foundation of China(Nos.22271154,M-0411);the Fundamental Research Funds for the Central Universities(No.NG2022003).
Compartmentalization in the biological world brings excellent efficiency and specificity to the formation of complex compounds,inspiring supramolecular chemists to continuously search for defined spaces that can mimic...
关键词：RESORCINARENE CAVITAND Supramolecular chemistry Host-guest chemistry Molecular recognition 
C-H…X-C bonds in alkyl halides drive reverse selectivities in confined spaces
《Chinese Chemical Letters》2023年第5期237-240,共4页Manuel Petroselli Yong-Qing Chen Ming-Kai Zhao Julius Rebek Jr. Yang Yu 
supported by the National Natural Science Foundation of China(Nos.22071144 and 21801164);Shanghai Scientific and Technological Committee(No.22010500300);the Program for Professor of Special Appointment(Dongfang Scholaship)of the Shanghai Education Committee。
Binding of non-activated alkyl halides(2-20)in water-soluble cavitand(1)through supramolecular forces is here reported,with emphasis on the role of size and polarizability of the halogen atom in the formation of intra...
关键词：Water-soluble cavitand Host-guest complex Molecular recognition C-H hydrogen bond Alkyl halides 
Metal coordination to a deep cavitand promotes binding selectivities in water
《Chinese Chemical Letters》2022年第11期4908-4911,共4页Yong-Qing Chen Hua-Wei Guan Kuppusamy Kanagaraj Julius Rebek Yang Yu 
supported by the National Natural Science Foundation of China(Nos.22071144 and 21801164);Shanghai University(No.13-G210-20-201);the Program for Professor of Special Appointment(Dongfang Scholarship)of the Shanghai Education Committee。
One goal of supramolecular chemistry is the creation of synthetic receptors that have a high affinity for hydrophilic molecules in water.We found that cavitands with upper rims extended by pyridyl groups coax hydrophi...
关键词：Host-guest chemistry Metallo cavitand Hydrophilic small molecules Molecular recognition Water-soluble containers 
Shape Selectivity of a Metallo Cavitand Host Allows Separation of n-Alkanes from Isooctane
《Chinese Journal of Chemistry》2021年第6期1498-1502,共5页Yun-Hui Wan Faiz-Ur Rahman Julius Rebek Jr. Yang Yu 
the National Natural Science Foundation of China(Nos.21801164 and 22071144);Shanghai University(N.13-G210-20-201).Dr.Yang Yu thanks the Program for Professor of Special Appointment(Dongfang Scholarship)of the Shanghai Education Committee.
The use of a metallo cavitand for the selective sequestration of n-alkanes from their mixtures with isooctane is described.Competition experiments and NMR spectroscopy are used to show the preference of a water-solubl...
关键词：Metallo cavitand Shape selectivity eceptor Alkane separation Host-guest system 
类杯芳烃孔穴桥联双芘分子开关化合物被引量：3
《高等学校化学学报》2015年第12期2421-2426,共6页徐海 赵斯祺 任扬 蔡健峰 汪翔 林雨霖 
国家自然科学基金(批准号:21002127;212501100517)资助~~
利用构型可变的分子开关类杯芳烃孔穴化合物(Cavitand)作为母体,合成了2种具有不同臂长的双芘Cavitand化合物.在室温及中性状态下,2种双芘Cavitand化合物均可检验出分子内激基复合物荧光,其中短臂双芘Cavitand化合物的荧光明显强于长臂C...
关键词：分子开关 类杯芳烃孔穴化合物 荧光 双芘Cavitand化合物 
Synthesis and Molecular Structure of a C-iso-Butyl-cavitand Bowl with Trimethyl and Methylol Groups
《Chinese Journal of Structural Chemistry》2005年第4期444-448,共5页LIUShu-Qun YAOWen-Rui ZHANGQian-Feng 
This project was supported by the Key Scientific Research Foundation of State Education Ministry of China (No. 204067)
A C-iso-butyl-cavitand bowl with trimethyl and methylol groups was isolated from the acetoxymethyl hydrolysis of mono-methylbromo-cavitand in THF. The molecular structure of the present cavitand compound was determi...
关键词：structure RESORCINARENE CAVITAND supramolecular chemistr 
Synthesis and Crystal Structure of Macrocyclic Cavitand Cu-curbit[5]uril and Its Supramolecular Adduct with Cu(II)被引量：2
《Chinese Journal of Chemistry》2004年第10期1208-1210,共3页刘思敏 黄子祥 吴晓军 梁峰 吴成泰 
Project supported by the National Natural Science Foundation of China (No. 20172040).
The first supramolecular adduct (H3O)2[Cu(H2O)4](SO4)2?(C30H30N20O10)?4(H2O) based on cucurbit[5]uril was synthesized and characterized by single crystal X-ray diffraction analysis. In the adduct, copper ion is coordi...
关键词：CUCURBIT[5]URIL crystal structure supramolecular adduct 
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