One-Pot Process of Anthraquinone Synthesis in the Presence of Mo-V-P Heteropoly Acid Solutions as a Bifunctional Catalysts  

作　　者：Leonid Gogin Elena Zhizhina 

机构地区：[1]Boreskov Institute of Catalysis, Novosibirsk, Russia

出　　处：《Modern Research in Catalysis》2013年第3期90-92,共3页催化剂现代研究（英文）

摘　　要：Acid-catalytic 1,3-butadiene condensation with para-quinones followed by the obtained product oxidation may be performed in one stage as one-pot process, if assisted by the aqueous solutions of Mo-V-P heteropoly acids with a composition of HaPzMoyVxOb. 1,4-naphthoquinone condensation with 1,3-butadiene in the HPA solutions with no organic solvents yields 9,10-anthraquinone (AQ) mixed with tetrahydro-AQ (THA) and dihydro-AQ (DHA). However, AQ yield and its purity may be considerably improved by using water-mixable organic solvents, e.g., acetone, 1,4-dioxane, as well as high vanadium content HPA such as H15P4Mo18V7O89 and H17P3Mo16V10O89. Process optimization provides 70% yield of reaction product containing no less than 90% AQ.Acid-catalytic 1,3-butadiene condensation with para-quinones followed by the obtained product oxidation may be performed in one stage as one-pot process, if assisted by the aqueous solutions of Mo-V-P heteropoly acids with a composition of HaPzMoyVxOb. 1,4-naphthoquinone condensation with 1,3-butadiene in the HPA solutions with no organic solvents yields 9,10-anthraquinone (AQ) mixed with tetrahydro-AQ (THA) and dihydro-AQ (DHA). However, AQ yield and its purity may be considerably improved by using water-mixable organic solvents, e.g., acetone, 1,4-dioxane, as well as high vanadium content HPA such as H15P4Mo18V7O89 and H17P3Mo16V10O89. Process optimization provides 70% yield of reaction product containing no less than 90% AQ.

关 键 词：9 10-Anthraquinone Mo-V-P HETEROPOLY Acids DIENE SYNTHESIS Organic Solvents 

分 类 号：O6[理学—化学]