国家自然科学基金(s20374043)

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相关期刊:《Chinese Journal of Polymer Science》更多>>
相关主题:METALLOCENESIRBRIDGEDNOVELMETALLOCENE更多>>
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SYNTHESIS OF NOVEL THIOPHENEDIMETHYLENE BRIDGED HOMOBINUCLEAR METALLOCENES AND THEIR CATALYTIC PROPERTIES FOR ETHYLENE POLYMERIZATION
《Chinese Journal of Polymer Science》2006年第1期21-27,共7页Xi-jie Liu Jun-quan Sun Hai-ying Zhang Xiao-hui Xiao and Feng Lin Department of Chemical Engineering,College of Material and Chemical Engineering,Zhejiang University,Hangzhou 310027,China 
This work was financially supported by the National Natural Science Foundation of China(Nos.20374043,20074028)China Petroleum & Chemical Corporation(No.X503027).
By treating disodium(thiophenedimethylene)dicyclopentadienide C4H2S(CH2C5H4Na)2 with two equivalent of CpTiCl3 or CpZrC13 DME at 0℃ in THF, two new thiophenedimethylene bridged binuclear metallocenes [Cl2MC5H5][C...
关键词:Binuclear metallocene Thiophenedimethylene bridged Ethylene polymerization. 
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