国家自然科学基金(21101040)

作品数:10被引量:37H指数:5
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相关作者:何辉薛云张志俭陈丽军曹鹏更多>>
相关机构:哈尔滨工程大学中国原子能科学研究院更多>>
相关期刊:《物理化学学报》《无机化学学报》《Journal of Rare Earths》《Acta Metallurgica Sinica(English Letters)》更多>>
相关主题:MG-LILICLALLOYSMGCLKCL更多>>
相关领域:理学一般工业技术金属学及工艺轻工技术与工程更多>>
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氯化物熔盐体系中Gd的电化学行为及提取效率的评估被引量:1
《物理化学学报》2015年第5期920-926,共7页杨晓南 颜永得 张密林 李星 薛云 韩伟 
国家自然科学基金(21103033,21101040,91226201,51104050);中国和黑龙江博士后特别资助科学基金(2013T60344,LBH-TZ0411);中央高校基本科研业务经费(HEUCF20151007);黑龙江省普通高等学校和哈尔滨工程大学青年学术骨干支持计划项目(1253G016,HEUCFQ1415)资助~~
研究了773 K时Gd Cl3在Li Cl-KCl熔盐体系中在Mo和Al电极上的电化学行为和热力学特性.利用开路计时电位曲线得到了Gd(III)/Gd(0)体系在723-873 K温度范围的平衡电极电位和表观电极电位.结果表明:平衡电极电位和表观电极电位随着温度的...
关键词:熔盐 吉布斯自由能变 活度系数 提取效率 电解提取 
Electrochemical reduction of Tm ions in LiCl-KCl melt at liquid Zn electrodes
《Nuclear Science and Techniques》2015年第1期103-107,共5页颜永得 李星 薛云 唐浩 纪德彬 韩伟 张密林 张志俭 
Supported by the High Technology Research and Development Program of China(No.2011AA03A409);the National Natural Science Foundation of China(Nos.21103033,21101040,and 91226201);the Fundamental Research funds for the Central Universities(No.HEUCF141502);the Foundation for University Key Teacher of Heilongjiang Province of China and Harbin Engineering University(Nos.1253G016 and HEUCFQ1415);the Special Foundation of China and Heilongjiang Postdoctoral Science Foundation(Nos.2013T60344 and LBH-TZ0411)
The reduction of Tm(Ⅲ) on a liquid Zn electrode was investigated in a Li Cl-KCl melt via cyclic voltammetry,square wave voltammetry, and open circuit chronopotentiometry. On a liquid Zn electrode, the reduction mecha...
关键词:电化学还原 锌电极 铥离子 氯化钾 氯化锂 ZN 熔液 金属间化合物 
在LiCl-KCl-AlCl_3熔盐中直接电化学还原Sm_2O_3及Al-Sm合金的形成(英文)被引量:8
《无机化学学报》2013年第9期1947-1951,共5页薛云 王倩 颜永得 陈浪 张密林 张志俭 
国家自然基金(No.21103033,21101040,91226201);黑龙江省高校青年学术骨干支持计划(No.1253G016);中国博士后科学基金特别资助(No.2013T60344);中央高校基本科研业务费(No.HEUCF131502)资助项目
在803 K LiCl-KCl熔盐中,研究了通过添加助剂AlCl3直接电化学还原Sm2O3和Al-Sm合金的形成。以SmCl3为原料作为参照,采用循环伏安和方波伏安方法,研究了Sm2O3在LiCl-KCl-AlCl3熔盐体系中的电化学行为。通过对比发现在两个体系中,峰的数...
关键词:  合金 电化学 LiCl-KCl熔盐 电沉积 
MgCl_2在LiCl-KCl熔盐中的电化学特性(英文)被引量:9
《物理化学学报》2013年第8期1698-1704,共7页唐浩 颜永得 张密林 薛云 张志俭 杜卫超 何辉 
supported by the High Technology Research and Development Program of China(2011AA03A409);National Natural Science Foundation of China(21103033,21101040,91226201);China Postdoctoral Science Foundation(2013T60344);Fundamental Research Funds for the Central Universities,China(HEUCF201310012);Foundation for University Key Teacher of Heilongjiang Province of China(1253G016)~~
研究了温度范围在723-908K的LiCl-KCl熔盐体系中MgCl2的电化学行为和热力学性质.循环伏安和方波伏安法研究表明镁离子的电化学还原过程为包含了两个电子转移的一步反应.利用Berzins和Delahay方程计算了不同温度下的镁离子的扩散系数,并...
关键词:氯化物熔盐 热力学性质 MGCL2 活度系数 标准形式电位 
Electrodeposition of quarternary Mg-Zn-Li-Ca alloys from molten salts被引量:1
《Transactions of Nonferrous Metals Society of China》2013年第3期861-865,共5页曹鹏 张密林 韩伟 颜永得 陈丽军 
Project(2011AA03A409) supported by the High-tech Research and Development Program of China;Projects(21103033,21101040, 21173060,91226201) supported by the National Natural Science Foundation of China;Project(HEUCF20130012) supported by the Fundamental Research Funds for the Central Universities,China;Project(1253G016) supported by the Foundation for University Key Teacher of Heilongjiang Province of China
Direct electrodeposition of quarternary Mg-Zn-Li-Ca alloys on a molybdenum electrode from LiCl-KCl-MgCl2-ZnCl2-CaCl2 melts at 943 K was investigated.Cyclic voltammograms(CVs) show that the deposition potential of Li...
关键词:Mg-Zn-Li-Ca alloys ELECTROLYSIS cyclic voltammetry molten salt 
Electrochemical formation of Mg-Li-Y alloys by co-deposition of magnesium, lithium and yttrium ions in molten chlorides被引量:6
《Journal of Rare Earths》2012年第10期1048-1054,共7页薛云 颜永得 张密林 韩伟 张志俭 
Project supported by the National 863 Project of the Ministry of Science and Technology of China (2011AA03A409);National Natural Science Foundation of China (21103033, 21101040 and 91226201);the Fundamental Research Funds for the Central Universities (HEUCF201210002);the Basic Research Foundation of Harbin Engineering University of China (HEUFT08030);the Heilongjiang Postdoctoral Fund (LBH-Z10196 and LBH-Z10207);the China Postdoctoral Science Foundation (20100480974)
An electrochemical approach for the preparation of Mg-Li-Y alloys via co-reduction of Mg, Li, and Y on a molybdenum electrode in LiCl-KCl-MgCl2-YCl3 melts at 943 K was investigated. Cyclic voltammograms (CVs) illumi...
关键词:Mg-Li-Y alloys electrochemical codeposition molten salt cyclic voltammetry rare earths 
Preparation of ternary Mg-Li-Sn alloys from molten salt by electrolysis被引量:2
《Acta Metallurgica Sinica(English Letters)》2012年第4期265-271,共7页Peng CAO Milin ZHANG Wei HAN Yongde YAN Lijun CHEN 
financially supported by National High Technical Research and Development Programme of China (Nos. 2011AA03A409 and 2009AA050702);National Basic Research Program of China (No. 2007CB200906);the National Natural Science Foundation of China (Nos. 21103033,21101040 and 21173060);the Fundamental Research Funds for the Central Universities
Electrochemical behavior of Mg, Li and Sn on tungsten electrodes in LiC1-KC1-MgCI2- SnC12 melts at 873 K was investigated. Cyclic voltammograms (CVs) showed that the underpotential deposition (UPD) of magnesium on...
关键词:Mg-Li-Sn alloy Molten salt Cyclic voltammetry ELECTROLYSIS 
Mn(Ⅱ)在LiCl-KCl-MgCl_2-MnCl_2熔盐体系中的电化学行为被引量:5
《高等学校化学学报》2012年第2期327-330,共4页陈丽军 张密林 韩伟 颜永得 曹鹏 
国家自然科学基金(批准号:21101040,21173060,21103033)资助
采用循环伏安和计时电位等电化学技术研究了Mn(Ⅱ)在LiCl-KCl-MgCl2-MnCl2熔盐体系中的电还原过程和Mg-Li-Mn合金的共沉积条件.结果显示,在LiCl-KCl-MgCl2-MnCl2熔盐体系中,Mn(Ⅱ),Mg(Ⅱ)和Li(Ⅰ)的还原电位分别为-1.14,-1.78和-2.19 V...
关键词:LiCl-KCl-MgCl2-MnCl2熔盐体系 循环伏安 计时电位 扩散系数 Mg-Li-Mn合金 
Electrochemical study on preparation of Mg-Li-Yb alloys in LiCl-KCl-KF-MgCl_2-Yb_2O_3 melts被引量:1
《Journal of Rare Earths》2012年第2期159-163,共5页陈丽军 张密林 韩伟 颜永得 曹鹏 
Project supported by the National Natural Science Foundation of China (21103033, 21101040 and 21173060);the Fundamental Research funds for the Central Universities (HEUCF101210002);863 projects (2011AA03A409, 2009AA050702)
This paper presented a novel study on electrochemical codeposition of Mg-Li-Yb alloys in LiCl-KCl-KF-MgCl2-Yb2O3 melts on molybdenum. The factors of the current efficiency were investigated. Electrolysis temperature h...
关键词:current efficiency electrochemical codeposition Mg-Li-Yb alloys INTERMETALLIC rare earths 
Preparation of Mg-Li-La alloys by electrolysis in molten salt被引量:8
《Transactions of Nonferrous Metals Society of China》2012年第1期16-22,共7页ZHANG Mi-lin CAO Peng HAN Wei YAN Yong-de CHEN Li-jun 
Projects (2009AA050702, 2011AA03A409, 2007CB200906) supported by Hi-tech Research and Development Program of China;Projects (21103033, 21101040, 21173060) supported the National Natural Science Foundation of China;Project (HEUCF201210002) supported the Fundamental Research Funds for the Central Universities, China
An electrochemical method was used to prepare Mg-Li-La alloys in a molten LiCl-KCl-KF-MgCl2 containing La2O3 at 943 K. The results showed preparation of Mg-Li-La alloys by electrolysis is feasible. The Mg-Li-La alloys...
关键词:Mg-Li-La alloys LA2O3 ELECTROLYSIS MICROSTRUCTURE 
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