supported by the national natural science foundation of China (No 20771034);Henan Innovation Project for University Prominent Research Talents;the Natural Science Foundation of Henan Province (No 0524480020)
A new sandwich transition metal substituted polyoxotungstate, [NH3(CH2)4NH3]6[Co4(H2O)2(B-α-GeW9O34)2]}·7H2O 1, was hydrothermaUy synthesized and characterized by IR spectra and single-crystal X-ray diffractio...
the Specialized Research Fund for the Doctoral Program of Higher Education(No.20040475001);Henan Inno-vation Project for University Prominent Research Talents, and the Natural Science Foundation of Henan Province, China (No.0524480020)
The reaction of α-H3[PW12O40] with Y(NO3)3 in the presence of DMF or DMSO leads to two complexes with the formulae {Y(DMSO)7}·PW12O40(1) and {[Y(DMF)7]2PW12O40}·PW12O40(2). The crystal structures indicate...
The project was supported by Henan Innovation Project for University Prominent Research Talents;the Natural Science Foundation of Henan Province (No.0524480020);Natural Science Foundation of Henan University (No. XK04YBRW057)
The synthesis, X-ray crystal structure, thermal properties and electrochemistry of the new complex formulated as {Er(DMSO)7}PW12O40 are reported. The single-crystal X-ray analysis reveals that the crystal crystalliz...