国家自然科学基金(20971004)

作品数:26被引量:39H指数:3
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相关作者:刘光祥任小明黄荣谊王彦徐衡更多>>
相关机构:安庆师范学院南京大学南京晓庄学院南京工业大学更多>>
相关期刊:《Journal of Rare Earths》《光谱实验室》《无机化学学报》《Chinese Journal of Structural Chemistry》更多>>
相关主题:晶体结构荧光性质CRYSTAL_STRUCTURE镉配合物锌配合物更多>>
相关领域:理学一般工业技术金属学及工艺更多>>
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新型8-氨基喹啉锌配合物的合成及其荧光性能被引量:3
《合成化学》2015年第7期619-622,共4页徐衡 朱昌海 薛晨 姜灏 黄荣谊 赵顺平 
国家自然科学基金资助项目(20971004);安徽高校省级自然科学研究重点项目(KJ2010A229)
以8-氨基喹啉,高氯酸锌和叠氮酸钠为原料,通过溶剂热反应合成了一种新型的单核配合物[Zn(8-aminoql)2(N3)]·Cl O4(1),其结构经FT-IR,元素分析和X-射线单晶衍射表征。1(CCDC:1 028 430)属单斜晶系,P2/c空间群,晶胞参数a=8.445 2(7),b=...
关键词:8-氨基喹啉 锌配合物 合成 晶体结构 荧光性能 
以烟酸为配体的铜配合物的合成、晶体结构及磁学性质(英文)被引量:4
《无机化学学报》2013年第9期1914-1920,共7页刘光祥 
国家自然科学基金(No.20971004,21271106);教育部科学技术重点项目(No.210102)资助项目
以氯化铜和烟酸(Hnic)为原料,在水热条件下得到了一个配位聚合物[Cu2(nic)4(H2O)]n(1),并利用元素分析、红外光谱以及X-射线单晶洐射对其进行了表征。该晶体属单斜晶系,P21/c空间群,a=1.071 56(3)nm,b=1.958 79(6)nm,c=1.379 50(3)nm,β...
关键词:铜配合物 烟酸 晶体结构 磁性 
Synthesis, Crystal Structure, Luminescence Property and DFT Calculations of a New Coordination Compound Containing 8-Aminoquinoline Ligand被引量:1
《Chinese Journal of Structural Chemistry》2013年第4期545-549,共5页徐衡 刘光祥 黄荣谊 赵顺平 孔学军 
supported by the National Natural Science Foundation of China(No.20971004);the Natural Science Foundation of Anhui Provincial Educational Commission(No.KJ2010A229,No.2011SQRL098)
A new luminescent compound, Zn(8-aminoql)2(SCN)2 (1, 8-aminoql = 8-amino quinoline), has been synthesized and its structure was characterized by IR, elemental analysis and X-ray single-crystal diffraction. Compo...
关键词:zinc compound crystal structure PHOTOLUMINESCENCE DFT 
A Novel Two-dimensional Homochiral Zinc(Ⅱ) Complex Constructed Based on In Situ Ligand Formation
《Chinese Journal of Structural Chemistry》2012年第10期1501-1506,共6页赵秀琴 郭畅 黄荣谊 徐衡 刘光祥 吴根华 
supported by the National Natural Science Foundation of China (No. 20971004, 21171008);the Natural Science Foundation of Anhui Provincial Educational Commission (No. KJ2010A2229);the Outstanding Youth Foundation of Anhui Provincial Education Commission (No. 2010SQRL108ZD)
A novel zinc(II) complex, Zn(IBT)2 (1, H1BT = 5-(4-((1H-imidazol-1-yl)methyl)- phenyl)-2H-tetrazole) has been synthesized with Zn(NO3)2·6H2O, 4-(imidazol-l-ylmethyl)benzonnitrile (IBN) and NaN3 by t...
关键词:zinc complex in situ ligand synthesis crystal structure PHOTOLUMINESCENCE DFT 
8-氨-基喹啉镉配合物溶液的荧光性质
《光谱实验室》2012年第5期3238-3241,共4页徐衡 郭畅 郭丽敏 黄荣谊 
国家自然科学基金(No.20971004);安徽省自然科学基金(No.KJ2010A2229)
采用荧光光谱法研究不同溶剂对两种8-氨基喹啉镉配合物溶液荧光性能的影响。结果表明,在极稀溶液中,发光体结构发生改变,相对与固体配合物而言,溶液荧光波长均向短波位移;不同溶剂中溶液荧光强度和波长均有较大的改变,主要是溶剂极性影...
关键词:8-氨-基喹啉配合物 溶剂效应 荧光性质 
A 4d-4f heterometallic coordination polymer: Synthesis, crystal structure and near-infrared luminescent properties被引量:1
《Journal of Rare Earths》2012年第7期716-720,共5页刘光祥 
Project supported by National Natural Science Foundation of China (20971004);the Key Project of Chinese Ministry of Education (210102)
A 4d-4f heterometallic coordination polymer, [AgNd(pydc)2].2H2O (1) (H2pydc=pyridine-3,4-dicarboxylic acid), was synthesized under hydrothermal conditions, and fimher characterized by elemental analysis, IR, the...
关键词:Heterometallic coordination polymer pyridine-3 4-dicarboxylic acid crystal structure near-infrared luminescence rare earths 
Synthesis, Structure and Luminescent Properties of a New Terbium(Ⅲ) Complex with 5-Bromoisophthalic Acid被引量:8
《Chinese Journal of Structural Chemistry》2012年第2期173-178,共6页刘光祥 查筱春 李杏龙 
Supported by the National Natural Science Foundation of China (No. 20971004);the Key Project of Chinese Ministry of Education (No. 210102)
The self-assembly of 5-bromoisophthalic acid (H2BIPA) with Tb(NO3)3·6H2O under hydrothermal conditions gives rise to a 3D coordination polymer, [Tb2(BIPA)3(CH3CH2OH)]n (1), which was characterized by elemen...
关键词:Tb(Ⅲ) coordination polymer crystal structure 5-bromoisophthalic acid LUMINESCENCE 
Synthesis,structure and near-infrared luminescence of a new 2D praseodymium(Ⅲ) coordination polymer被引量:2
《Journal of Rare Earths》2011年第11期1100-1104,共5页刘光祥 周宏 任小明 
Project supported by the National Natural Science Foundation of China (20971004);the Key Project of Chinese Ministry of Education (210102)
A novel coordination polymer,[Pr2(BIPA)3(H2O)2].2H2O(1)(H2BIPA=5-bromoisophthalic acid),was prepared by hydrothermal synthesis and characterized by IR spectroscopy,elemental analysis and single-crystal X-ray d...
关键词:Pr(Ⅲ) coordination polymer 5-bromoisophthalic acid crystal structure near-infrared luminescence rare earths 
Synthesis and Crystal Structure of a Cobalt(Ⅱ) Coordination Polymer with Benzene-1,3,5-triacetate and 1,2-Di(pyridin-4-yl)ethene被引量:2
《Chinese Journal of Structural Chemistry》2011年第9期1239-1244,共6页刘光祥 李杏龙 任小明 
supported by the National Natural Science Foundation of China (No. 20971004);the Natural Science Foundation of Anhui Province (No. 11040606M45)
A novel coordination polymer, [Co3(bta)2(dpe)3(H2O)2]·2H2O (1, H3bta = benzene-1,3,5-triacetic acid, and dpe = 1,2-di(pyridin-4-yl)ethene), has been hydrothermally prepared and characterized by IR spectrosc...
关键词:cobalt coordination polymer crystal structure benzene-1 3 5-triacetic acid 
咪唑[4,5-f]1,10-邻菲罗啉及其2-取代芳基衍生物的电子结构与光谱性质被引量:1
《原子与分子物理学报》2011年第4期598-606,共9页王来国 黄荣谊 
国家自然科学基金(20971004);安徽高校省级自然科学基金重点项目(KJ2010A229);安徽高校省级优秀青年人才基金(2010SQRL108ZD)
分别采用B3LYP/6-31G(d)和CIS/6-31G(d)方法对咪唑[4,5-f]1,10-邻菲罗啉(ip)及其8种2-取代芳基衍生物的基态(S_0)和单重激发态(S_1)的几何构型进行了全优化,并采用含时的度泛函理论(TD-DFT)计算了上述化合物的电子吸收和电子发射光谱....
关键词:邻菲罗啉衍生物 前线轨道 电子结构 电子光谱 密度泛函理论 
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