This work was supported by the National Natural Science Foundation of China (No. 20271011)
A new compound [Cu(I)(phen)2]5[HV15O36(Cl)]0.65[H3V16O38(Cl)]0.35·2H2O 1 (phen = 1,10′-phenanthroline) has been prepared from the hydrothermal reaction of V2O5, CuCl, phen, H2C2O4·2H2O, THMAM (tris(hydr...