国家自然科学基金(20271043)

作品数:15被引量:18H指数:3
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相关作者:江崇球石敬民王洪鉴魏薇张立伟更多>>
相关机构:山东师范大学更多>>
相关期刊:《分析化学》《无机化学学报》《Chinese Journal of Structural Chemistry》更多>>
相关主题:ANIONCRYSTAL_STRUCTURESLIGANDCRYSTAL_STRUCTURETHIOCYANATE更多>>
相关领域:理学医药卫生更多>>
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Synthesis and Crystal Structure of a Three-dimensional Mn(Ⅱ) Coordination Polymer with 3-(Pyrazin-2-yloxy)-pyridine and Azide Anion as Mixed Bridge Ligand被引量:1
《Chinese Journal of Structural Chemistry》2008年第12期1511-1513,共3页李红 赵红艳 张士国 石敬民 
Supported by the National Natural Science Foundation of China (No. 20271043);Natural Science Foundation of Shandong Province (Y2007B26)
A three-dimensional coordination polymer [Mn2(μ1.3-N3)4(μ-PP)2]n (PP = 3-(pyrazin-2-yloxy)-pyridine) has been synthesized with 3-(pyrazin-2-yloxy)-pyridine and azide anion as mixed bridge ligand, and its c...
关键词:II Synthesis and Crystal Structure of a Three-dimensional Mn Coordination Polymer with 3 Pyrazin-2-yloxy pyridine and Azide Anion as Mixed Bridge Ligand 
2,6-二乙氧基-β-环糊精对铕(Ⅲ)-强力霉素络合物包合作用的研究及其分析应用被引量:5
《分析化学》2008年第11期1547-1550,共4页张立伟 罗黎 江崇球 石敬民 
国家自然科学基金(No.20271043)资助项目
在pH=9.4的NH4Cl-NH3·H2O的缓冲溶液条件下,强力霉素能与铕(Ⅲ)生成二元络合物并发射出铕(Ⅲ)位于612 nm处的特征荧光,加入2,6-二乙氧基-β-环糊精后,体系的荧光强度显著增强,且增强的荧光强度与强力霉素的浓度呈线性关系,据此建立了...
关键词:荧光光度法 铕(Ⅲ) 强力霉素 2 6-二乙氧基-β-环糊精 
喹诺酮类药物与铜锌超氧化物歧化酶的相互作用及其对酶活性的影响被引量:3
《分析化学》2008年第8期1040-1044,共5页魏薇 王洪鉴 江崇球 石敬民 
国家自然科学基金(No.20271043)资助项目
利用紫外-可见吸收光谱和荧光光谱,在pH=7.4的生理条件下,研究了喹诺酮类药物(依诺沙星、环丙沙星和诺氟沙星)与铜锌超氧化物歧化酶(CuZnSOD)的相互作用。喹诺酮类药物能使CuZnSOD的荧光发生猝灭,其猝灭机理为静态猝灭。通过实验计算了...
关键词:喹诺酮类药物 铜锌超氧化物歧化酶 荧光分光光度法 
新型荧光试剂1,5-二(4,6-二氯三嗪)-氨基萘与酪氨酸相互作用被引量:3
《分析化学》2007年第12期1772-1775,共4页魏薇 王洪鉴 江崇球 石敬民 
国家自然科学基金(No.20271043)资助
合成了一种新型三嗪荧光探针1,5-二(4,6-二氯三嗪)-氨基萘并利用元素分析、IR和核磁共振谱进行了表征。在pH=12.0的柠檬酸钠·NaOH缓冲溶液中,与酪氨酸在35℃下反应30min后,λex/λem=400nm/465nm处,1,5-二(4,6-二氯三嗪)...
关键词:荧光光度法 酪氨酸 1 5-二(4 6-二氯三嗪)-氨基萘 
铽(Ⅲ)、铕(Ⅲ)-1-环丙基-6-氟-7(1-哌嗪基)1、4-二氢-4-氧喹啉-3-羧酸-乙酰丙酮三元固体荧光配合物的合成与光谱表征被引量:6
《无机化学学报》2007年第9期1635-1638,共4页冯林 江崇球 石敬民 
国家自然科学基金资助项目(No.20271043)。
0引言 镧系离子以其独特的光、电、磁、催化和分析等作用而受到人们的广泛关注,并进行了大量的研究。镧系离子本身发光效率低,目前,设计并合成含有稀土离子Tb^3+和Eu^3+的超分子配合物,作为发光分子器件和荧光探针成为稀土配位化学...
关键词:铽(Ⅲ)配合物 铕(Ⅲ)配合物 环丙沙星 乙酰丙酮 
Syntheses and Crystal Structures of Two Coordination Polymers with Aromatic Dioxide as Bridge Ligands
《Chinese Journal of Structural Chemistry》2007年第2期214-218,共5页SHI Jing-Min XU Hai-Yan ZHANG Feng-Xia WU Chang-Ju LIU Lian-Dong 
This work was supported by the National Natural Science Foundation of China (No. 20271043);Natural Science Foundation of Shandong Province (Y2005B25)
Two coordination polymers, namely, two-dimensional complex 1 {[Cu(μ- L)1.5(ClO4)2(H2O)].(H2O)0.5]n (L = pyrazine-1,4-dioxide) and one-dimensional complex 2 [Co(μ-L)Br2(H2O)2]n, have been synthesized wi...
Syntheses and Crystal Structures of Two Two-dimensional Coordination Polymers with 2,3-Dimethylpyrazine-1,4-dioxide and Thiocyanate as Mixed Bridge Ligands
《Chinese Journal of Structural Chemistry》2007年第1期118-120,共3页石敬民 李伟男 张凤霞 张霞 刘连栋 
This work was supported by the National Natural Science Foundation of China (No. 20271043) and the Natural Science Foundation of Shandong Province (Y2005B25)
Two two-dimensional coordination polymers, [Cd(μ1,3-SCN-)2(μ1,6-L)]n 1 and [Co(μ1,3-SCN-)2(μ1,6-L)]n 2, have been synthesized with 2,3-dimethylpyrazine-1,4-dioxide (L) and thiocyanate as mixed bridging l...
关键词:crystal structure cadmium(Ⅱ) complex pyrazine dioxide THIOCYANATE 
Syntheses,Crystal Structures and Fluorescence of Cadmium(II) Coordination Polymers with Pyrazine-1,4-dioxide, 2-Methylpyrazine-1,4-dioxide and Thiocyanate as Mixed Bridge Ligands
《Chinese Journal of Structural Chemistry》2006年第10期1238-1242,共5页SHI Jing-Min ZHANG Feng-Xia ZHANG Xia XU Hai-Yan LIU Lian-Dong MA Jian-Ping 
This work was supported by the National Natural Science Foundation of China (No. 20271043) and Natural Science Foundation of Shandong Province (Y2005B25)
Two Cd(Ⅱ) coordination polymers have been synthesized with pyrazine-1,4-dioxide (L1), 2-methylpyrazine-1,4-dioxide (L2), and thiocyanate anion as mixed bridge ligands. Crystal data for complex 1 [Cd(μ1,3-SCN^...
Synthesis and Crystal Structure of a Three-dimensional Cd(II) Coordination Polymer [Cd(μ_(1,3)-SCN)(μ_3-pco)]_n(pco=Pyrazine-2-carboxylate 4-oxide Anion)
《Chinese Journal of Structural Chemistry》2006年第8期937-939,共3页SHI Jing-Min XU Hong-Kun WU Chang-Ju LIU Lian-Dong 
This work was supported by the National Natural Science Foundation of China (20271043) and Natural Science Foundation of Shandong Province (Y2005B25)
The three-dimensional complex [Cd(μ1,3-SCN)(μ3-pco)]n has been synthesized with μ1,3-SCN^- and pco as mixed bridged ligands. The crystal belongs to monoclinic, space group P21/n with a = 10.3777(16), b = 6.2...
关键词:synthesis crystal structure cadmium(Ⅱ) complex THIOCYANATE aromatic N-oxide 
Synthesis,Crystal Structure and Fluorescence of a Three-dimensional Cd(II) Coordination Polymer [Cd(μ_(1,3)- SCN^-)_2(μ-dmpo)]_n (dmpo = 3,5-Dimethylpyridine N-Oxide)
《Chinese Journal of Structural Chemistry》2006年第7期779-782,共4页SHI Jing-Min ZHANG Feng-Xia HUANG Jie LIU Lian-Dong 
This work was supported by the National Natural Science Foundation of China (No. 20271043) and Natural Science Foundation of Shandong Province (Y2005B25)
A three-dimensional complex [Cd(μ1,3-SCN)2(dmpo)]n has been synthesized with μ1,3-SCN^- and dmpo as mixed bridge ligands. The crystal belongs to monoclinic, space group C2/c with a = 15.648(2), b = 15.126(2)...
关键词:crystal structure cadmium(Ⅱ) complex FLUORESCENCE aromatic N-oxide ligand thiocyanate ligand 
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